引用本文:
Yating Zhou, Anucha Koedtruad, Zhenhong Tan, Dong Zhang, Lingxiang Bao, Yajun Yue, Jianyuan Wu, Juping Xu, Yu-anguang Xia, Wen Yin, Maxim Avdeev, Wang Hay Kan, Takashi Kamiyama, Ping Miao. Solvent-free mechanochemical synthesis of organic proton conducting salts incorporating imidazole and dicarboxylic acids[J]. Chinese Journal of Structural Chemistry,
2023, 42(5): 100059.
doi:
10.1016/j.cjsc.2023.100059
Citation: Yating Zhou, Anucha Koedtruad, Zhenhong Tan, Dong Zhang, Lingxiang Bao, Yajun Yue, Jianyuan Wu, Juping Xu, Yu-anguang Xia, Wen Yin, Maxim Avdeev, Wang Hay Kan, Takashi Kamiyama, Ping Miao. Solvent-free mechanochemical synthesis of organic proton conducting salts incorporating imidazole and dicarboxylic acids[J]. Chinese Journal of Structural Chemistry, 2023, 42(5): 100059. doi: 10.1016/j.cjsc.2023.100059
Citation: Yating Zhou, Anucha Koedtruad, Zhenhong Tan, Dong Zhang, Lingxiang Bao, Yajun Yue, Jianyuan Wu, Juping Xu, Yu-anguang Xia, Wen Yin, Maxim Avdeev, Wang Hay Kan, Takashi Kamiyama, Ping Miao. Solvent-free mechanochemical synthesis of organic proton conducting salts incorporating imidazole and dicarboxylic acids[J]. Chinese Journal of Structural Chemistry, 2023, 42(5): 100059. doi: 10.1016/j.cjsc.2023.100059
Solvent-free mechanochemical synthesis of organic proton conducting salts incorporating imidazole and dicarboxylic acids
摘要:
Solventless mechanochemical synthesis by manual grinding was applied to grow imidazole-succinic acid (C3H4N2HOOC-(CH2)2COOH) and imidazole-glutaric acid (C3H4N2HOOC-(CH2)3COOH), which exhibit different electric conducting behaviors and activation energies Ea compared with the reported single crystals obtained from the solution method. This method bears strong capability for tuning conductivities and achieves complete deuteration of the organic salts.
English
Solvent-free mechanochemical synthesis of organic proton conducting salts incorporating imidazole and dicarboxylic acids
Abstract:
Solventless mechanochemical synthesis by manual grinding was applied to grow imidazole-succinic acid (C3H4N2HOOC-(CH2)2COOH) and imidazole-glutaric acid (C3H4N2HOOC-(CH2)3COOH), which exhibit different electric conducting behaviors and activation energies Ea compared with the reported single crystals obtained from the solution method. This method bears strong capability for tuning conductivities and achieves complete deuteration of the organic salts.
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