ADSORPTION OF HUMIC SUBSTANCES BY MACRO WEAKLY BASIC ION-EXCHANGE RESIN AND THEIR EFFECTS ON REMOVAL OF Cu2+ AND Pb2+

Jin-nan Wang a b Yang Zhou a b Ai-min Li a b Li Xu a b Ling Xu a b

Citation:  Jin-nan Wang a, b, Yang Zhou a, b, Ai-min Li a, b, Li Xu a, b, Ling Xu a, b. ADSORPTION OF HUMIC SUBSTANCES BY MACRO WEAKLY BASIC ION-EXCHANGE RESIN AND THEIR EFFECTS ON REMOVAL OF Cu2+ AND Pb2+[J]. Chinese Journal of Polymer Science, 2010, 28(3): 427-435. doi: 10.1007/s10118-010-9050-9 shu

ADSORPTION OF HUMIC SUBSTANCES BY MACRO WEAKLY BASIC ION-EXCHANGE RESIN AND THEIR EFFECTS ON REMOVAL OF Cu2+ AND Pb2+

摘要: Adsorption of humic, tannic and gallic acids by a macro weakly basic ion-exchange resin JN-01 was studied. The adsorption capacity of this resin for gallic and tannic acids is much higher than that for humic acid, which can be explained on the basis of both their molecular size and ionization degree. Furthermore, humic acid is separated into different components with molecular weight in the range from 2000 Da to 100000 Da by ultra-filter, and their adsorption isotherms on resin JN-01 indicate that humic acids molecular weight is an important factor which makes significant influence on adsorption. Finally, changes in the amount of Cu2+ and Pb2+ adsorbed on resin JN-01 as a function of the concentration of each of these three acids were studied. A large increase in the heavy metal ions uptake is observed in the presence of humic substance, such advantages are due to the interactions between the heavy metal ions and the unbound functional groups of the adsorbed organic acids.

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  • 发布日期:  2010-05-20
  • 收稿日期:  2009-04-07
  • 修回日期:  2009-05-13
通讯作者: 陈斌, bchen63@163.com
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