面向非富勒烯型有机光伏电池的聚合物给体材料设计

引用本文: 张少青, 侯剑辉. 面向非富勒烯型有机光伏电池的聚合物给体材料设计[J]. 物理化学学报, 2017, 33(12): 2327-2338. doi: 10.3866/PKU.WHXB201706161 shu

Citation: ZHANG Shao-Qing, HOU Jian-Hui. Rational Design Strategies for Polymer Donors for Applications in Non-Fullerene Organic Photovoltaic Cells[J]. Acta Physico-Chimica Sinica, 2017, 33(12): 2327-2338. doi: 10.3866/PKU.WHXB201706161 shu

面向非富勒烯型有机光伏电池的聚合物给体材料设计

张少青 ^1,2, ,
侯剑辉 ^2,

1.
北京科技大学化学与生物工程学院, 北京 100083;
2.
中国科学院化学研究所, 北京分子科学国家实验室, 高分子物理与化学实验室, 北京 100190
基金项目:
国家自然科学基金委（91333204，21325419，51673201）和中国科学院战略性B类先导科技专项（XDB12030200）

摘要: 可溶液加工的有机光伏电池（OPV）是一种具有重要应用潜力的新型光伏技术。在OPV技术的发展过程中，富勒烯衍生物作为电子受体材料占据了相当长时间的统治地位，因此聚合物给体材料设计中对如何与富勒烯受体材料相互匹配考虑较多。最近几年来，基于聚合物给体和非富勒烯有机受体的OPV电池，简称为非富勒烯型NF-OPV，得到了十分快速的发展。在此类电池中，聚合物电子给体和非富勒烯型电子受体材料均起到了十分重要的作用。相比于较为经典的富勒烯型OPV，NF-OPV对聚合物给体的光电特性和聚集态结构提出了新的要求。因此，本文针对NF-OPV的特点，重点介绍NF-OPV对聚合物给体材料的吸收光谱、分子能级以及聚集态结构等特征的新要求，总结最近几年来的相关进展，并在此基础上进一步讨论聚合物电子给体材料面临的挑战和展望。

关键词:

English

Rational Design Strategies for Polymer Donors for Applications in Non-Fullerene Organic Photovoltaic Cells

ZHANG Shao-Qing ^1,2, ,
HOU Jian-Hui ^2,

1.
School of Chemistry and Biology Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2.
State Key Laboratory of Polymer Physics and Chemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
Received Date: 29 May 2017
Revised Date: 11 June 2017
Fund Project:
The project was supported by National Nature Science Foundation of China (91333204,21325419,51673201) and the Chinese Academy of Sciences (XDB12030200).

Abstract: Solution-processable organic photovoltaic cells (OPVs) have attracted considerable interest.Over the past twenty years,fullerene and its derivatives have been predominately used as the electron acceptor materials to fabricate OPV devices.In recent few years,non-fullerene organic photovoltaic cells (NF-OPVs),consisting of polymers as the donors and the non-fullerene (NF) materials as the acceptors,have been developed rapidly,and the highest power conversion efficiencies of NF-OPVs exceed those of fullerene-based OPVs.In these NF-OPVs,both polymeric donor materials and NF acceptors play critical roles in achieving outstanding efficiencies,and hence,the molecular design of the polymer donors has been deemed a very important topic of research in the field.In this review,we will present an introduction of the specific requirements for polymer donors in NF-OPVs and summarize the recent progress related to polymer donors for the applications in highly efficient NF-OPVs.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

面向非富勒烯型有机光伏电池的聚合物给体材料设计

English

Rational Design Strategies for Polymer Donors for Applications in Non-Fullerene Organic Photovoltaic Cells

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中国化学会秘书处

面向非富勒烯型有机光伏电池的聚合物给体材料设计

English

Rational Design Strategies for Polymer Donors for Applications in Non-Fullerene Organic Photovoltaic Cells

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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