High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene

Qian CHENG Takayuki ORITANI Alfred HASSNER

引用本文: Qian CHENG,  Takayuki ORITANI,  Alfred HASSNER. High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene[J]. Chinese Chemical Letters, 1999, 10(8): 629-632. shu
Citation:  Qian CHENG,  Takayuki ORITANI,  Alfred HASSNER. High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene[J]. Chinese Chemical Letters, 1999, 10(8): 629-632. shu

High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene

  • 基金项目:

    We are thankful to Professor X. T. Liang for his useful help on the analysis of NMR. Financial support by Monbusho Grant-in-Aid from Iapan Society for the Promotion of Science and calculations made in University of Washington, USA are acknowledged.

摘要: Modest to high diastereoselectivites have been observed in the conjugate addition of functionalized alcohols to chiral (E)-nitroalkene 1 depending on the presence of metal catalysts at low temperature. The results indicated that the anti-form had been preferred in all cases.

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  • 收稿日期:  1999-03-12
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