引用本文:
Qian CHENG, Takayuki ORITANI, Alfred HASSNER. High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene[J]. Chinese Chemical Letters,
1999, 10(8): 629-632.
Citation: Qian CHENG, Takayuki ORITANI, Alfred HASSNER. High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene[J]. Chinese Chemical Letters, 1999, 10(8): 629-632.
Citation: Qian CHENG, Takayuki ORITANI, Alfred HASSNER. High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene[J]. Chinese Chemical Letters, 1999, 10(8): 629-632.
High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene
摘要:
Modest to high diastereoselectivites have been observed in the conjugate addition of functionalized alcohols to chiral (E)-nitroalkene 1 depending on the presence of metal catalysts at low temperature. The results indicated that the anti-form had been preferred in all cases.
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关键词:
- Diastereoselectivity
- / michael addition
- / alcohols
- / catalysts
English
High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene
Abstract:
Modest to high diastereoselectivites have been observed in the conjugate addition of functionalized alcohols to chiral (E)-nitroalkene 1 depending on the presence of metal catalysts at low temperature. The results indicated that the anti-form had been preferred in all cases.
-
Key words:
- Diastereoselectivity
- / michael addition
- / alcohols
- / catalysts
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