Citation:
Yong Cui, Shu Zhang, Wen-hua Sun. SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF DIMERIC Co(II) AND Ni(II) COMPLEXES CONTAINIGN N,N'-(PHENYL-2-PYRIDINYLMETHYLENE)-3,3',5,5'-TETRAMETHYLBENZIDINE[J]. Chinese Journal of Polymer Science,
2008, 26(5): 539-545.
SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF DIMERIC Co(II) AND Ni(II) COMPLEXES CONTAINIGN N,N'-(PHENYL-2-PYRIDINYLMETHYLENE)-3,3',5,5'-TETRAMETHYLBENZIDINE
摘要:
The N,N'-(phenyl-2-pyridinylmethylene)-3,3',5,5'-tetramethylbenzidine and its dimeric Co(II) and Ni(II) complexes were synthesized. The organic compound was characterized by elemental analyses, IR and NMR spectra, while the bimetal complexes were determined by elemental analyses, IR spectra as well as the single-crystal X-ray diffraction. The nickel complex showed high activity for ethylene polymerization and its cobalt analogue showed negligible active in ethylene activation.
English
SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF DIMERIC Co(II) AND Ni(II) COMPLEXES CONTAINIGN N,N'-(PHENYL-2-PYRIDINYLMETHYLENE)-3,3',5,5'-TETRAMETHYLBENZIDINE
Abstract:
The N,N'-(phenyl-2-pyridinylmethylene)-3,3',5,5'-tetramethylbenzidine and its dimeric Co(II) and Ni(II) complexes were synthesized. The organic compound was characterized by elemental analyses, IR and NMR spectra, while the bimetal complexes were determined by elemental analyses, IR spectra as well as the single-crystal X-ray diffraction. The nickel complex showed high activity for ethylene polymerization and its cobalt analogue showed negligible active in ethylene activation.
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