镍基碳纳米纤维无酶葡萄糖电化学传感器的研究

引用本文: 陈汉, 孙健航, 杨国程. 镍基碳纳米纤维无酶葡萄糖电化学传感器的研究[J]. 分析化学, 2021, 49(6): 1008-1014. doi: 10.19756/j.issn.0253-3820.211091 shu

Citation: CHEN Han, SUN Jian-Hang, YANG Guo-Cheng. Fabrication of Non-enzymatic Glucose Electrochemical Sensor Based on Nickel-base Carbon Nanofibers[J]. Chinese Journal of Analytical Chemistry, 2021, 49(6): 1008-1014. doi: 10.19756/j.issn.0253-3820.211091 shu

镍基碳纳米纤维无酶葡萄糖电化学传感器的研究

长春工业大学化学与生命科学学院, 材料科学高等研究院, 长春 130012
基金项目:
国家自然科学基金项目（No.20105008）和吉林省教育厅科技计划项目（No.JJKH20170544KJ）资助。

摘要: 以静电纺丝制得Ni和NiMoO₄纳米棒掺杂的聚乙烯醇（PVA）碳纳米纤维（CNF），以此两种碳纳米纤维为前驱体，分别进行高温碳化，制备了Ni-CNF和Ni-Mo₂C-CNF复合材料。对所制备材料的组成和形貌进行了表征，探究了两种材料对葡萄糖的直接电催化性能，结果表明，Ni-CNF和Ni-Mo₂C-CNF对葡萄糖均表现出良好的电催化性能，基于Ni-Mo₂C-CNF构建的无酶葡萄糖传感器具有低响应电位（0.45 V）、高灵敏度（198 μA·mmol/（L·cm²））、宽线性范围（0.01~7.0 mmol/L）和低检出限（4.3 μmol/L），并且具有良好的稳定性、重现性和选择性。本研究为无酶葡萄糖传感器研究提供了参考。

关键词:

English

Fabrication of Non-enzymatic Glucose Electrochemical Sensor Based on Nickel-base Carbon Nanofibers

School of Chemistry and Life Science, Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, China
Received Date: 31 January 2021
Revised Date: 14 April 2021
Fund Project:
Supported by the National Natural Science Foundation of China (No.20105008) and the Science and Technology Program of the Education Department of Jilin Province, China (No.JJKH20170544KJ).

Abstract: Ni and NiMoO₄ nanorods doped polyvinyl alcohol (PVA) carbon nanofibers (CNF) were prepared by electrospinning technique. The two carbon nanofibers were used as precursors and carbonized at high temperature respectively to prepare Ni-CNF and Ni-Mo₂C-CNF composite materials. The composition and morphology of the prepared materials were characterized, and the direct electrocatalytic performance of the materials for glucose was investigated. The results showed that both Ni-CNF and Ni-Mo₂C-CNF showed good electrocatalytic performance for glucose. The non-enzymatic glucose sensor based on Ni-Mo₂C-CNF had low response potential (0.45 V), high sensitivity (198 μA·mmol/(L·cm²)), wide linear range (0.01-7.0 mmol/L), and low detection limit (4.3 μmol/L). Meanwhile, the non-enzymatic glucose sensor had good stability, reproducibility and selectivity. This study provided important practical reference value for the study of non-enzymatic glucose sensor.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

镍基碳纳米纤维无酶葡萄糖电化学传感器的研究

English

Fabrication of Non-enzymatic Glucose Electrochemical Sensor Based on Nickel-base Carbon Nanofibers

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

镍基碳纳米纤维无酶葡萄糖电化学传感器的研究

English

Fabrication of Non-enzymatic Glucose Electrochemical Sensor Based on Nickel-base Carbon Nanofibers

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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