Green Oxygenation Degradation of Rhodamine B by Using Activated Molecule Oxygen

Ke Jian DENG Fei HUANG Duo Yuan WANG Zheng He PENG Yun Hong ZHOU

引用本文: Ke Jian DENG,  Fei HUANG,  Duo Yuan WANG,  Zheng He PENG,  Yun Hong ZHOU. Green Oxygenation Degradation of Rhodamine B by Using Activated Molecule Oxygen[J]. Chinese Chemical Letters, 2004, 15(10): 1223-1226. shu
Citation:  Ke Jian DENG,  Fei HUANG,  Duo Yuan WANG,  Zheng He PENG,  Yun Hong ZHOU. Green Oxygenation Degradation of Rhodamine B by Using Activated Molecule Oxygen[J]. Chinese Chemical Letters, 2004, 15(10): 1223-1226. shu

Green Oxygenation Degradation of Rhodamine B by Using Activated Molecule Oxygen

  • 基金项目:

    The work was supported by the NNSFC (No.29771025) and (No.20377053) and The Nine-five National Key Project of China (29833090) and The Hubei Province Foundation of China (No.2003AB A071).

摘要: Iron(Ⅱ) tetra-(1,4-dithin)-porphyrazine, (FePz(dtn)4) is able to activate molecule oxygen for oxygenation degradation of rhodamine B (RhB) in an extensive pH region without light excitation. Experiments indicate that the RhB can be degraded nearly 52% in alkaline aqueous solution, bubbling with dioxygen for seven hours in the presence of FePz(dtn)4 and the hydrogen peroxides as an actve intermediate were determined by DPD method. The catalyst is recyclable and the catalyst activity was maintained after l0 recycles.

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  • 收稿日期:  2003-08-25
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