引用本文:
Jin Xiao MI, Shao Yu MAO, Zai Hong CHEN, Zhong Le HUANG, Jing Tai ZHAO. Synthesis and Structures of New Borophosphates (B1-XMX)PO4 (M=Mn,Fe,Co,Ni,Cu) with Orthorhombic Low-Cristobalite Type[J]. Chinese Chemical Letters,
1999, 10(8): 707-708.
Citation: Jin Xiao MI, Shao Yu MAO, Zai Hong CHEN, Zhong Le HUANG, Jing Tai ZHAO. Synthesis and Structures of New Borophosphates (B1-XMX)PO4 (M=Mn,Fe,Co,Ni,Cu) with Orthorhombic Low-Cristobalite Type[J]. Chinese Chemical Letters, 1999, 10(8): 707-708.
Citation: Jin Xiao MI, Shao Yu MAO, Zai Hong CHEN, Zhong Le HUANG, Jing Tai ZHAO. Synthesis and Structures of New Borophosphates (B1-XMX)PO4 (M=Mn,Fe,Co,Ni,Cu) with Orthorhombic Low-Cristobalite Type[J]. Chinese Chemical Letters, 1999, 10(8): 707-708.
Synthesis and Structures of New Borophosphates (B1-XMX)PO4 (M=Mn,Fe,Co,Ni,Cu) with Orthorhombic Low-Cristobalite Type
摘要:
The first reported (B1-xMx)PO4 (M=Mn. Fe. Co. Ni. Cu) compounds were synthesized by high temperature solid state methods and the structures refined from X-ray powder data. The transition metal substitutions on the boron site stabilized the structure to the orthorhombic low-cristobalite type with average volumes per tetrahedral unit 300% larger than that in BPO4 and novel catalytic properties are expected. The magnetic data indicate the 3+ valences for the metals.
English
Synthesis and Structures of New Borophosphates (B1-XMX)PO4 (M=Mn,Fe,Co,Ni,Cu) with Orthorhombic Low-Cristobalite Type
Abstract:
The first reported (B1-xMx)PO4 (M=Mn. Fe. Co. Ni. Cu) compounds were synthesized by high temperature solid state methods and the structures refined from X-ray powder data. The transition metal substitutions on the boron site stabilized the structure to the orthorhombic low-cristobalite type with average volumes per tetrahedral unit 300% larger than that in BPO4 and novel catalytic properties are expected. The magnetic data indicate the 3+ valences for the metals.
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Key words:
- Transition-metal borophosphate
- / synthesis
- / structure
- / magnetic property
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