Synthesis and Structures of New Borophosphates (B1-XMX)PO4 (M=Mn,Fe,Co,Ni,Cu) with Orthorhombic Low-Cristobalite Type

Jin Xiao MI Shao Yu MAO Zai Hong CHEN Zhong Le HUANG Jing Tai ZHAO

引用本文: Jin Xiao MI,  Shao Yu MAO,  Zai Hong CHEN,  Zhong Le HUANG,  Jing Tai ZHAO. Synthesis and Structures of New Borophosphates (B1-XMX)PO4 (M=Mn,Fe,Co,Ni,Cu) with Orthorhombic Low-Cristobalite Type[J]. Chinese Chemical Letters, 1999, 10(8): 707-708. shu
Citation:  Jin Xiao MI,  Shao Yu MAO,  Zai Hong CHEN,  Zhong Le HUANG,  Jing Tai ZHAO. Synthesis and Structures of New Borophosphates (B1-XMX)PO4 (M=Mn,Fe,Co,Ni,Cu) with Orthorhombic Low-Cristobalite Type[J]. Chinese Chemical Letters, 1999, 10(8): 707-708. shu

Synthesis and Structures of New Borophosphates (B1-XMX)PO4 (M=Mn,Fe,Co,Ni,Cu) with Orthorhombic Low-Cristobalite Type

  • 基金项目:

    This work was supported by the NNSFC. the NSF of Fujian province and the Fund from the State Key Laboratory for Crystal Materials at Shangdong University.

摘要: The first reported (B1-xMx)PO4 (M=Mn. Fe. Co. Ni. Cu) compounds were synthesized by high temperature solid state methods and the structures refined from X-ray powder data. The transition metal substitutions on the boron site stabilized the structure to the orthorhombic low-cristobalite type with average volumes per tetrahedral unit 300% larger than that in BPO4 and novel catalytic properties are expected. The magnetic data indicate the 3+ valences for the metals.

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  • 收稿日期:  1998-12-08
  • 修回日期:  1999-05-21
通讯作者: 陈斌, bchen63@163.com
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