引用本文:
Xiao Ming XIAO, Takeko MATSUMURA-INO UE. 99Ru and 13C-NMR Spectra for the Tris Chelates of 5-Substituted 1,10- Phenanthrolines with Ruthenium(Ⅱ)[J]. Chinese Chemical Letters,
1998, 9(8): 765-766.
Citation: Xiao Ming XIAO, Takeko MATSUMURA-INO UE. 99Ru and 13C-NMR Spectra for the Tris Chelates of 5-Substituted 1,10- Phenanthrolines with Ruthenium(Ⅱ)[J]. Chinese Chemical Letters, 1998, 9(8): 765-766.
Citation: Xiao Ming XIAO, Takeko MATSUMURA-INO UE. 99Ru and 13C-NMR Spectra for the Tris Chelates of 5-Substituted 1,10- Phenanthrolines with Ruthenium(Ⅱ)[J]. Chinese Chemical Letters, 1998, 9(8): 765-766.
99Ru and 13C-NMR Spectra for the Tris Chelates of 5-Substituted 1,10- Phenanthrolines with Ruthenium(Ⅱ)
摘要:
13C and 99Ru-NMR chemical shifts are reported for the ruthenium(Ⅱ) tris complexes of 5-substituted 1,10-phenanthrolines. It has been found that both of them are affected by the substituents on the phenanthrolines in a direction consistent with that expected from the electron withdrawing ability of the substituent.
English
99Ru and 13C-NMR Spectra for the Tris Chelates of 5-Substituted 1,10- Phenanthrolines with Ruthenium(Ⅱ)
Abstract:
13C and 99Ru-NMR chemical shifts are reported for the ruthenium(Ⅱ) tris complexes of 5-substituted 1,10-phenanthrolines. It has been found that both of them are affected by the substituents on the phenanthrolines in a direction consistent with that expected from the electron withdrawing ability of the substituent.
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Key words:
- NMR spectrum
- / ruthenium(Ⅱ) complex
- / substituent effect
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