引用本文:
Bin SUN, Li Zeng PENG, Xue Song CHEN, Yu Lin LI, Ying LI. A Short and Stereoselective Synthesis of the (-)-(5R,6S)-6-Acetoxy hexadecane-5-olide[J]. Chinese Chemical Letters,
2004, 15(10): 1177-1178.
Citation: Bin SUN, Li Zeng PENG, Xue Song CHEN, Yu Lin LI, Ying LI. A Short and Stereoselective Synthesis of the (-)-(5R,6S)-6-Acetoxy hexadecane-5-olide[J]. Chinese Chemical Letters, 2004, 15(10): 1177-1178.
Citation: Bin SUN, Li Zeng PENG, Xue Song CHEN, Yu Lin LI, Ying LI. A Short and Stereoselective Synthesis of the (-)-(5R,6S)-6-Acetoxy hexadecane-5-olide[J]. Chinese Chemical Letters, 2004, 15(10): 1177-1178.
A Short and Stereoselective Synthesis of the (-)-(5R,6S)-6-Acetoxy hexadecane-5-olide
摘要:
(-)-(5R, 6S)-6-Acetoxyhexadecan-5-olide 1, a natural mosquito attractant pheromone,was synthesized from readily available aldehyde 2 and cyclopentanone 3 using L-proline-catalyzed asymmetric aldol reaction as the key step.
English
A Short and Stereoselective Synthesis of the (-)-(5R,6S)-6-Acetoxy hexadecane-5-olide
Abstract:
(-)-(5R, 6S)-6-Acetoxyhexadecan-5-olide 1, a natural mosquito attractant pheromone,was synthesized from readily available aldehyde 2 and cyclopentanone 3 using L-proline-catalyzed asymmetric aldol reaction as the key step.
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Key words:
- 6-Acetoxyhexadecan-5-olide
- / Baeyer-Villiger oxidation
- / aldol reaction
- / L-proline
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