TiO2 nanotubes :A novel solid phase extraction adsorbent for the sensitive determination of nickel in environmental water samples

Xin Ning Zhao Qi Zeng Shi Guo Hong Xie Qing Xiang Zhou

引用本文: Xin Ning Zhao,  Qi Zeng Shi,  Guo Hong Xie,  Qing Xiang Zhou. TiO2 nanotubes :A novel solid phase extraction adsorbent for the sensitive determination of nickel in environmental water samples[J]. Chinese Chemical Letters, 2008, 19(7): 865-867. doi: 10.1016/j.cclet.2008.05.004 shu
Citation:  Xin Ning Zhao,  Qi Zeng Shi,  Guo Hong Xie,  Qing Xiang Zhou. TiO2 nanotubes :A novel solid phase extraction adsorbent for the sensitive determination of nickel in environmental water samples[J]. Chinese Chemical Letters, 2008, 19(7): 865-867. doi: 10.1016/j.cclet.2008.05.004 shu

TiO2 nanotubes :A novel solid phase extraction adsorbent for the sensitive determination of nickel in environmental water samples

  • 基金项目:

    the Fund of Henan Normal University (No.2006PL06) and the grants from the Henan Key Laboratory for environmental pollution control.

    Natural Science Foundation of Henan Province(No.072300460010)

    This work was supported by the Creative Talented Person’s Fund of Henan Province (No.[2005]126)

摘要: A novel method was developed for the sensitive determination of nickel in environmental water samples by using TiO2 nanotubes,a new nanomaterial,as solid phase extraction absorbent.In general,TiO2 nanomaterials were often used for catalytic degradation of pollutants in environmental field,and only a very few application in environmental analytic chemistry.In present work,TiO2 nanotubes was firstly used for the enrichment of nickel and the factors would influence the preconcentration performance were optimized.Under the optimal conditions,TiO2 nanotubes exhibited its good enrichment capacity for nickel and the detection limit of the proposed method was 1 ng mL-1.The proposed method was validated with real water samples,and excellent results were obtained with the spiked recoveries in the range of 94.4-99.2%,respectively.

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  • 收稿日期:  2007-12-18
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