引用本文:
Ming Zhong CAI, Hong ZHAO. Stereoselective Synthesis of (E)-1,3-Enynyl Bromides via Pd/Cu-catalyzed Cross-coupling Reaction of (Z)-α-Bromovinylstannanes[J]. Chinese Chemical Letters,
2004, 15(10): 1157-1160.
Citation: Ming Zhong CAI, Hong ZHAO. Stereoselective Synthesis of (E)-1,3-Enynyl Bromides via Pd/Cu-catalyzed Cross-coupling Reaction of (Z)-α-Bromovinylstannanes[J]. Chinese Chemical Letters, 2004, 15(10): 1157-1160.
Citation: Ming Zhong CAI, Hong ZHAO. Stereoselective Synthesis of (E)-1,3-Enynyl Bromides via Pd/Cu-catalyzed Cross-coupling Reaction of (Z)-α-Bromovinylstannanes[J]. Chinese Chemical Letters, 2004, 15(10): 1157-1160.
Stereoselective Synthesis of (E)-1,3-Enynyl Bromides via Pd/Cu-catalyzed Cross-coupling Reaction of (Z)-α-Bromovinylstannanes
摘要:
(Z)-α-Bromovinylstannanes undergo the cross-coupling reaction with alkynyl iodides in the presence of Pd(PPh3)4 and Cul in THF at room temperature to afford stereoselectively (E)-1, 3-enynyl bromides in good yields
English
Stereoselective Synthesis of (E)-1,3-Enynyl Bromides via Pd/Cu-catalyzed Cross-coupling Reaction of (Z)-α-Bromovinylstannanes
Abstract:
(Z)-α-Bromovinylstannanes undergo the cross-coupling reaction with alkynyl iodides in the presence of Pd(PPh3)4 and Cul in THF at room temperature to afford stereoselectively (E)-1, 3-enynyl bromides in good yields
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Key words:
- (Z)-α-Bromovinylstannane
- / palladium
- / cross-coupling
- / stereoselective synthesis
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