引用本文:
Ali R. Kiasat, Maryam Zayadi, Mehdi Fallah Mehrjardi. Regioselective ring opening of epoxides using NH4SCN/silica sulfuric acid:An efficient approach for the synthesis of β-hydroxy thiocyanate under solvent-free conditions[J]. Chinese Chemical Letters,
2008, 19(6): 665-668.
doi:
10.1016/j.cclet.2008.04.004
Citation: Ali R. Kiasat, Maryam Zayadi, Mehdi Fallah Mehrjardi. Regioselective ring opening of epoxides using NH4SCN/silica sulfuric acid:An efficient approach for the synthesis of β-hydroxy thiocyanate under solvent-free conditions[J]. Chinese Chemical Letters, 2008, 19(6): 665-668. doi: 10.1016/j.cclet.2008.04.004
Citation: Ali R. Kiasat, Maryam Zayadi, Mehdi Fallah Mehrjardi. Regioselective ring opening of epoxides using NH4SCN/silica sulfuric acid:An efficient approach for the synthesis of β-hydroxy thiocyanate under solvent-free conditions[J]. Chinese Chemical Letters, 2008, 19(6): 665-668. doi: 10.1016/j.cclet.2008.04.004
Regioselective ring opening of epoxides using NH4SCN/silica sulfuric acid:An efficient approach for the synthesis of β-hydroxy thiocyanate under solvent-free conditions
摘要:
Silica sulfuric acid was developed as a stable and efficient heterogeneous catalyst in organic synthesis. This solid acid catalyzed the regioselective ring opening of epoxides by thiocyanate anion to give thiocyanohydrins as key intermediates in agricultural and pharmaceutical chemistry in high yields under solvent-free conditions.
English
Regioselective ring opening of epoxides using NH4SCN/silica sulfuric acid:An efficient approach for the synthesis of β-hydroxy thiocyanate under solvent-free conditions
Abstract:
Silica sulfuric acid was developed as a stable and efficient heterogeneous catalyst in organic synthesis. This solid acid catalyzed the regioselective ring opening of epoxides by thiocyanate anion to give thiocyanohydrins as key intermediates in agricultural and pharmaceutical chemistry in high yields under solvent-free conditions.
-
Key words:
- Silica sulfuric acid
- / Thiocyanohydrins
- / β-Hydroxy thiocyanate
- / Epoxide
- / Solvent-free
扫一扫看文章
计量
- PDF下载量: 1
- 文章访问数: 965
- HTML全文浏览量: 3
下载:
