Citation:
Cigdem Yolacan, Irem Kulu, Nuket Ocal. POLYMERIZATION OF 1-AZABICYCLO[4.2.0]OCTANE WITH CHIRAL TRICYCLIC AMINO ACID ESTERS FOR OBTAINING BIOMEDICAL MATERIALS[J]. Chinese Journal of Polymer Science,
2010, 28(1): 39-44.
POLYMERIZATION OF 1-AZABICYCLO[4.2.0]OCTANE WITH CHIRAL TRICYCLIC AMINO ACID ESTERS FOR OBTAINING BIOMEDICAL MATERIALS
摘要:
The cationic ring-opening polymerization of 1-azabicyclo[4.2.0]octane, commonly called conidine (1) was studied with some chiral tricyclic amino acid esters (6a-6f) as acylation agents to obtain optically active biopolymers (8a-8f) of the different masses. The structures of the new compounds were confirmed by FT-IR, UV and NMR, and the distribution index of the molecular weights of the polymers was determined from SEC measurements.
English
POLYMERIZATION OF 1-AZABICYCLO[4.2.0]OCTANE WITH CHIRAL TRICYCLIC AMINO ACID ESTERS FOR OBTAINING BIOMEDICAL MATERIALS
Abstract:
The cationic ring-opening polymerization of 1-azabicyclo[4.2.0]octane, commonly called conidine (1) was studied with some chiral tricyclic amino acid esters (6a-6f) as acylation agents to obtain optically active biopolymers (8a-8f) of the different masses. The structures of the new compounds were confirmed by FT-IR, UV and NMR, and the distribution index of the molecular weights of the polymers was determined from SEC measurements.
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