Citation:
ZHAO Weiguo, SHEN Yongjia, LI Yongfang, YANG Jing. SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES*[J]. Chinese Journal of Polymer Science,
1998, 16(3): 214-218.
SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES*
摘要:
A polymer containing bis(ethylenedithio)-tetrathiafulvalene moiety wassynthesized and its electrochemical properties were studied by cyclic voltammetry. Thecharge transfer complexes of the polymer with TCNQ and I_2 were obtained by chemicaloxidation in dichlorobenzene. All of them are semi-conductors. A film of the polymer wasobtained by casting. Its conductivity, after oxidation with iodine, is 2.24×10~(-6)S·cm~(-1)and its conducting state is stable in air.
English
SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES*
Abstract:
A polymer containing bis(ethylenedithio)-tetrathiafulvalene moiety wassynthesized and its electrochemical properties were studied by cyclic voltammetry. Thecharge transfer complexes of the polymer with TCNQ and I_2 were obtained by chemicaloxidation in dichlorobenzene. All of them are semi-conductors. A film of the polymer wasobtained by casting. Its conductivity, after oxidation with iodine, is 2.24×10~(-6)S·cm~(-1)and its conducting state is stable in air.
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