引用本文:
Yu Peng TIAN, Jie Ying WU, Fu Xin XIE, Shi Sheng NI. New Complex Nonlinear optical Crystal-Bis(4-methoxybenzaldehyde thiosemicarbazone) Zinc Chloride(ZnL2Cl2)[J]. Chinese Chemical Letters,
1998, 9(2): 215-217.
Citation: Yu Peng TIAN, Jie Ying WU, Fu Xin XIE, Shi Sheng NI. New Complex Nonlinear optical Crystal-Bis(4-methoxybenzaldehyde thiosemicarbazone) Zinc Chloride(ZnL2Cl2)[J]. Chinese Chemical Letters, 1998, 9(2): 215-217.
Citation: Yu Peng TIAN, Jie Ying WU, Fu Xin XIE, Shi Sheng NI. New Complex Nonlinear optical Crystal-Bis(4-methoxybenzaldehyde thiosemicarbazone) Zinc Chloride(ZnL2Cl2)[J]. Chinese Chemical Letters, 1998, 9(2): 215-217.
New Complex Nonlinear optical Crystal-Bis(4-methoxybenzaldehyde thiosemicarbazone) Zinc Chloride(ZnL2Cl2)
摘要:
The structure of ZnL2Cl2(L=4-methoxybenzaldehyde thiosemicarbazone) has been obtained by x-ray diffraction. The compound crystallized in space group Cc with Z=4, in a unit cell of dimensions, a=9.08909(10), b=22.1420(10), c=11.7890(10)Å; β=90.050(10)°, v=2374.6(12)Å3, Dc=1.552gcm-3. μ=1.463mm-1, R=0.0338, and Rw=0.0418. The structure contains individual ZnL2Cl2 distorted tetrahedral units in which L molecules are S-bonded as monodentate to the metal ions; chloride ions are also coordinated. The nonlinear optical properties of the zinc complex are also presented in this letter.
English
New Complex Nonlinear optical Crystal-Bis(4-methoxybenzaldehyde thiosemicarbazone) Zinc Chloride(ZnL2Cl2)
Abstract:
The structure of ZnL2Cl2(L=4-methoxybenzaldehyde thiosemicarbazone) has been obtained by x-ray diffraction. The compound crystallized in space group Cc with Z=4, in a unit cell of dimensions, a=9.08909(10), b=22.1420(10), c=11.7890(10)Å; β=90.050(10)°, v=2374.6(12)Å3, Dc=1.552gcm-3. μ=1.463mm-1, R=0.0338, and Rw=0.0418. The structure contains individual ZnL2Cl2 distorted tetrahedral units in which L molecules are S-bonded as monodentate to the metal ions; chloride ions are also coordinated. The nonlinear optical properties of the zinc complex are also presented in this letter.
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