引用本文:
Fu An WANG, Chang Sheng YANG, Wen Chang WANG, Yuan Li JIANG. INTERSECTION POINT RULE OF THE RETENTION VALUE AND NORMAL BOILING POINT OF THE HOMOLOGUES IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY[J]. Chinese Chemical Letters,
1991, 3(8): 637-640.
Citation: Fu An WANG, Chang Sheng YANG, Wen Chang WANG, Yuan Li JIANG. INTERSECTION POINT RULE OF THE RETENTION VALUE AND NORMAL BOILING POINT OF THE HOMOLOGUES IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY[J]. Chinese Chemical Letters, 1991, 3(8): 637-640.
Citation: Fu An WANG, Chang Sheng YANG, Wen Chang WANG, Yuan Li JIANG. INTERSECTION POINT RULE OF THE RETENTION VALUE AND NORMAL BOILING POINT OF THE HOMOLOGUES IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY[J]. Chinese Chemical Letters, 1991, 3(8): 637-640.
INTERSECTION POINT RULE OF THE RETENTION VALUE AND NORMAL BOILING POINT OF THE HOMOLOGUES IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY
摘要:
In this paper, a linear relationship between the logarithm of capacity factor k' and normal boiling point to of the homologues has been derived, based on the basic retention equation of liquid chromatography according to statistical thermodyoamics proposed by professor Ln Peizhang and others, This equation has been verified by a large number of experimental data, all the strsight lines of lnk'--tb of bumologues for different mobile phass coaiposltion cross each other at the same point, So the intereection point equation was proposed, wbich was used to prodict the retention value, the result was satisfactory.
English
INTERSECTION POINT RULE OF THE RETENTION VALUE AND NORMAL BOILING POINT OF THE HOMOLOGUES IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY
Abstract:
In this paper, a linear relationship between the logarithm of capacity factor k' and normal boiling point to of the homologues has been derived, based on the basic retention equation of liquid chromatography according to statistical thermodyoamics proposed by professor Ln Peizhang and others, This equation has been verified by a large number of experimental data, all the strsight lines of lnk'--tb of bumologues for different mobile phass coaiposltion cross each other at the same point, So the intereection point equation was proposed, wbich was used to prodict the retention value, the result was satisfactory.
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 1486
- HTML全文浏览量: 45
下载:
