Citation:
HU Jiachong, JIN Yiming. WAXD STUDY OF POLYMORPHOUS ISOTACTICPOLYPROPYLENE BY COMPUTER PEAK-RESOLUTION METHOD*[J]. Chinese Journal of Polymer Science,
1985, 3(3): 204-215.
WAXD STUDY OF POLYMORPHOUS ISOTACTICPOLYPROPYLENE BY COMPUTER PEAK-RESOLUTION METHOD*
摘要:
Polymorphous i-PP containing a and β phases were studied by WAXD and computer peak-resolution method (CPRM). The asymmetric Gaussian-Cauchy functions (a-GC) were adoptedto fit the profiles of both amorphous and crystalline peaks. For the crystalline peaks, the fitting resultsof a-GC are better than the symmetric-GC; for the amorphous peaks, they are better than polynomialand exponential functions, etc. Using the retarded least-square procedure (RLSP) on microcom-puter the results of peak-resolution are rather satisfatory.For the polymorphous samples containing αand β phases,the relations between phase-state,crystallinity,crystalline size,the ratio of α,β relative content and the crystallization temperature Tc were studied by CPRM.The ratio of α,β relative contents obtained by CPRM and Turner-Jones eq have been carefully compared.There are many improvements in this work.A simple estimation method of WAXD peak areas,both for amorphous and crystalline peaks,is suggested.
English
WAXD STUDY OF POLYMORPHOUS ISOTACTICPOLYPROPYLENE BY COMPUTER PEAK-RESOLUTION METHOD*
Abstract:
Polymorphous i-PP containing a and β phases were studied by WAXD and computer peak-resolution method (CPRM). The asymmetric Gaussian-Cauchy functions (a-GC) were adoptedto fit the profiles of both amorphous and crystalline peaks. For the crystalline peaks, the fitting resultsof a-GC are better than the symmetric-GC; for the amorphous peaks, they are better than polynomialand exponential functions, etc. Using the retarded least-square procedure (RLSP) on microcom-puter the results of peak-resolution are rather satisfatory.For the polymorphous samples containing αand β phases,the relations between phase-state,crystallinity,crystalline size,the ratio of α,β relative content and the crystallization temperature Tc were studied by CPRM.The ratio of α,β relative contents obtained by CPRM and Turner-Jones eq have been carefully compared.There are many improvements in this work.A simple estimation method of WAXD peak areas,both for amorphous and crystalline peaks,is suggested.
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 1526
- HTML全文浏览量: 21

下载: