磷钨酸纳米ZSM-5复合催化剂的氧化脱硫反应性

陈立东 刘迪 牛思祺 姜春杰 刘丽萍 王祥生 朱江

引用本文: 陈立东, 刘迪, 牛思祺, 姜春杰, 刘丽萍, 王祥生, 朱江. 磷钨酸纳米ZSM-5复合催化剂的氧化脱硫反应性[J]. 应用化学, 2016, 33(3): 364-366. doi: 10.11944/j.issn.1000-0518.2016.03.150339 shu
Citation:  CHEN Lidong, LIU Di, NIU Siqi, JIANG Chunjie, LIU Liping, WANG Xiangsheng, ZHU Jiang. Oxidative Desulfurization of Organic Sulfides over Phosphotungstic Acid/Nano-ZSM-5 Composite Catalyst[J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 364-366. doi: 10.11944/j.issn.1000-0518.2016.03.150339 shu

磷钨酸纳米ZSM-5复合催化剂的氧化脱硫反应性

    通讯作者: 陈立东,讲师;Tel:0411-82156915;Fax:0411-82158329;E-mail:lidongchhm0809@163.com;研究方向:多酸催化;能源化工;朱江,讲师;Tel:0411-82156915;Fax:0411-82158329;E-mail:zjryan@163.com;研究方向:分子筛合成; 陈立东,讲师;Tel:0411-82156915;Fax:0411-82158329;E-mail:lidongchhm0809@163.com;研究方向:多酸催化;能源化工;朱江,讲师;Tel:0411-82156915;Fax:0411-82158329;E-mail:zjryan@163.com;研究方向:分子筛合成
  • 基金项目:

    辽宁省博士科研启动基金项目(20131060) 

摘要: 采用浸渍法制备了纳米晶ZSM-5负载的磷钨酸复合固体催化剂,纳米晶ZSM-5上单独负载磷钨酸时,Keggin结构磷钨酸转变为Dawson结构多酸化合物,结合镍盐后Keggin结构保持不变。以有机硫化物氧化脱硫为探针反应的研究结果表明,在低温(40℃)反应条件下,含二苯并噻吩有机硫组分的正辛烷模拟油品的脱硫率高达94.5%。

English

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  • 收稿日期:  2015-09-18
  • 网络出版日期:  2015-10-26
通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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