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铁酸锰/腐植酸复合材料制备及其对亚甲基蓝吸附性能

靳廷甲 ,  章祥林 ,  徐建

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引用本文: 靳廷甲, 章祥林, 徐建. 铁酸锰/腐植酸复合材料制备及其对亚甲基蓝吸附性能[J]. 应用化学, 2016, 33(3): 336-342. doi: 10.11944/j.issn.1000-0518.2016.03.150257 shu
Citation:  JIN Tingjia, ZHANG Xianglin, XU Jian. Preparation of Manganese Ferrite/Humic Acid Composite and Its Adsorption Properties for Methylene Blue[J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 336-342. doi: 10.11944/j.issn.1000-0518.2016.03.150257 shu

铁酸锰/腐植酸复合材料制备及其对亚甲基蓝吸附性能

  • a.

    a. 安徽建筑大学材料与化学工程学院 合肥 230601;

  • b.

    b. 安徽省先进建筑材料重点实验室 合肥 230022

    • 通讯作者: 章祥林,教授;Tel/Fax:0551-63513997;E-mail:jtingjia@126.com;研究方向:环境功能材料的制备与应用
  • 基金项目:

    安徽省长三角联合科技攻关项目（1101c0603053) 

    安徽建筑大学校级科技创新基金项目（201310878016）资助 

摘要: 采用化学共沉淀法合成了一种腐植酸（Humic Acid，HA）包覆铁酸锰型磁性复合材料（MnFe2O4/HA）。采用扫描电子显微镜（SEM）、粉末X射线衍射（XRD）和傅里叶变换红外光谱（FT-IR）等技术手段对其进行表征和分析表明，合成产物颗粒大小约200 nm，具有典型的尖晶石结构，腐植酸成功包覆在MnFe2O4颗粒表面，饱和磁化强度为34.01 A·m2/kg，在外界低磁场作用下30 s内便可从水溶液分离。MnFe2O4/HA对亚甲基蓝的吸附是一个准二级动力学过程，在2 h达到平衡，较好的符合Langmuir吸附模型。与MnFe2O4相比其对亚甲基蓝的吸附能力显著增强，室温下pH=9时最大吸附量可以达到29.94 mg/g。MnFe2O4/HA可以作为一种有效去除水体中亚甲基蓝污染物的吸附材料。

English

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    1. [1] JIN Xiaoying,CHEN Haibin,WANG Qingping,et al. The Mechanism of Methylene Blue Adsorbed by SDBS Modified Zeolite[J]. Technol Water Treat,2009,35(12):58-63(in Chinese).金晓英,陈海斌,王清萍,等. SDBS改性沸石吸附亚甲基蓝的性能研究[J]. 水处理技术,2009,35(12):58-63.[1] JIN Xiaoying,CHEN Haibin,WANG Qingping,et al. The Mechanism of Methylene Blue Adsorbed by SDBS Modified Zeolite[J]. Technol Water Treat,2009,35(12):58-63(in Chinese).金晓英,陈海斌,王清萍,等. SDBS改性沸石吸附亚甲基蓝的性能研究[J]. 水处理技术,2009,35(12):58-63.

    2. [2] MA Jie,YU Linlin,JING Lu,et al. The Mechanism of Methylene Blue Adsorbed by Carbon Nanotubes Modified the Original Sample[J]. Environ Chem,2012,31(5):646-652(in Chinese).马杰,虞琳琳,金路,等. 改性碳纳米管原始样品吸附亚甲基蓝的性能研究[J]. 环境化学,2012,31(5):646-652.[2] MA Jie,YU Linlin,JING Lu,et al. The Mechanism of Methylene Blue Adsorbed by Carbon Nanotubes Modified the Original Sample[J]. Environ Chem,2012,31(5):646-652(in Chinese).马杰,虞琳琳,金路,等. 改性碳纳米管原始样品吸附亚甲基蓝的性能研究[J]. 环境化学,2012,31(5):646-652.

    3. [3] LEI Xiaoling,HUANG Fang,CHEN Yao,et al. The Mechanism of Typical Dyes Adsorbed by Activated Carbon[J]. Ind Water Treat,2013,33(5):57-60(in Chinese).雷晓玲,黄芳,陈垚,等. 活性炭对典型染料的吸附性能研究[J]. 工业水处理,2013,33(5):57-60.[3] LEI Xiaoling,HUANG Fang,CHEN Yao,et al. The Mechanism of Typical Dyes Adsorbed by Activated Carbon[J]. Ind Water Treat,2013,33(5):57-60(in Chinese).雷晓玲,黄芳,陈垚,等. 活性炭对典型染料的吸附性能研究[J]. 工业水处理,2013,33(5):57-60.

    4. [4] ZHAO Ying,WANG Renguo,ZENG Wu,et al. The Preparation of Nanometer Manganese Dioxide and Its Research on Adsorption of Methylene Blue[J]. Technol Water Treat,2012,38(1):55-58(in Chinese).赵颖,王仁国,曾武,等. 纳米二氧化锰的制备及其对亚甲基蓝的吸附研究[J]. 水处理技术,2012,38(1):55-58.[4] ZHAO Ying,WANG Renguo,ZENG Wu,et al. The Preparation of Nanometer Manganese Dioxide and Its Research on Adsorption of Methylene Blue[J]. Technol Water Treat,2012,38(1):55-58(in Chinese).赵颖,王仁国,曾武,等. 纳米二氧化锰的制备及其对亚甲基蓝的吸附研究[J]. 水处理技术,2012,38(1):55-58.

    5. [5] ZHANG Jia,REN Bingxiong,WANG Peng,et al. The Mechanism of Methylene Blue Adsorbed by Camellia Seed Powder[J]. Environ Chem,2013,32(8):1539-1544(in Chinese).张佳,任秉雄,王鹏,等. 山茶籽粉吸附亚甲基蓝的性能研究[J]. 环境化学,2013,32(8):1539-1544.[5] ZHANG Jia,REN Bingxiong,WANG Peng,et al. The Mechanism of Methylene Blue Adsorbed by Camellia Seed Powder[J]. Environ Chem,2013,32(8):1539-1544(in Chinese).张佳,任秉雄,王鹏,等. 山茶籽粉吸附亚甲基蓝的性能研究[J]. 环境化学,2013,32(8):1539-1544.

    6. [6] HUANG Manwen,LIU Jingyong,CAI Huamei,et al. Adsorption Properties of Methylene Blue Adsorbed by Shaddock Peel[J]. Guizhou Agric Sci,2012,40(1):143-147(in Chinese).黄曼雯,刘敬勇,蔡华梅,等. 柚子皮对亚甲基蓝的吸附性能[J]. 贵州农业科学,2012,40(1):143-147.[6] HUANG Manwen,LIU Jingyong,CAI Huamei,et al. Adsorption Properties of Methylene Blue Adsorbed by Shaddock Peel[J]. Guizhou Agric Sci,2012,40(1):143-147(in Chinese).黄曼雯,刘敬勇,蔡华梅,等. 柚子皮对亚甲基蓝的吸附性能[J]. 贵州农业科学,2012,40(1):143-147.

    7. [7] LIU Jingyong,HUANG Guihong,DENG Junqiang,et al. Experimental Study on the Adsorption of Methylene Blue by Sugarcane Bagasse[J]. J Guangdong Tech Univ,2013,30(2):123-128(in Chinese).刘敬勇,黄桂虹,邓俊强,等. 甘蔗渣对亚甲基蓝的吸附性能实验研究[J]. 广东工业大学学报,2013,30(2):123-128.[7] LIU Jingyong,HUANG Guihong,DENG Junqiang,et al. Experimental Study on the Adsorption of Methylene Blue by Sugarcane Bagasse[J]. J Guangdong Tech Univ,2013,30(2):123-128(in Chinese).刘敬勇,黄桂虹,邓俊强,等. 甘蔗渣对亚甲基蓝的吸附性能实验研究[J]. 广东工业大学学报,2013,30(2):123-128.

    8. [8] YAO Chao,LIU Min,LI Weimin,et al. Adsorption Properties of Methylene Blue by the Composite of the Concave and Convex/Zinc Oxide Nano Composites[J]. Acta Sci Circumst,2010,30(6):1211-1219(in Chinese).姚超,刘敏,李为民,等. 凹凸棒石/氧化锌纳米复合材料对亚甲基蓝的吸附性能[J]. 环境科学学报,2010,30(6):1211-1219.[8] YAO Chao,LIU Min,LI Weimin,et al. Adsorption Properties of Methylene Blue by the Composite of the Concave and Convex/Zinc Oxide Nano Composites[J]. Acta Sci Circumst,2010,30(6):1211-1219(in Chinese).姚超,刘敏,李为民,等. 凹凸棒石/氧化锌纳米复合材料对亚甲基蓝的吸附性能[J]. 环境科学学报,2010,30(6):1211-1219.

    9. [9] CHENG Shaoxin. Introduction to Humic Substances[M]. Beijing:Chemical Industry Press,2007:21-22(in Chinese).成绍鑫. 腐植酸类物质概论[M]. 北京:化学工业出版社,2007:21-22.[9] CHENG Shaoxin. Introduction to Humic Substances[M]. Beijing:Chemical Industry Press,2007:21-22(in Chinese).成绍鑫. 腐植酸类物质概论[M]. 北京:化学工业出版社,2007:21-22.

    10. [10] ZHOU Xiaping. Chemical Basis of Application of Humic Acid[M]. Beijing:Chemical Industry Press,2007:21-22(in Chinese).周霞萍. 腐植酸应用中的化学基础[M]. 北京:化学工业出版社,2007:50-51.[10] ZHOU Xiaping. Chemical Basis of Application of Humic Acid[M]. Beijing:Chemical Industry Press,2007:21-22(in Chinese).周霞萍. 腐植酸应用中的化学基础[M]. 北京:化学工业出版社,2007:50-51.

    11. [11] AI Lunhong,JIANG Jing,TANG Juan. Preparation of Activated Carbon/CoFe2O4 Composite and Its Adsorption Properties for Methylene Blue[J]. Chinese J Appl Chem,2010,27(6):710-715(in chinese).艾伦弘,蒋静,唐娟. 活性碳/CoFe2O4复合物的制备及其对亚甲基蓝的吸附性能[J]. 应用化学,2010,27(6):710-715.[11] AI Lunhong,JIANG Jing,TANG Juan. Preparation of Activated Carbon/CoFe2O4 Composite and Its Adsorption Properties for Methylene Blue[J]. Chinese J Appl Chem,2010,27(6):710-715(in chinese).艾伦弘,蒋静,唐娟. 活性碳/CoFe2O4复合物的制备及其对亚甲基蓝的吸附性能[J]. 应用化学,2010,27(6):710-715.

    12. [12] Xu J C,Xin P H,Xin Y Q,et al. Magnetic Properties and Methylene Blue Adsorptive Performance of CoFe2O4/Activated Carbon Nanocomposites[J]. Mater Chem Phys,2014,147(3):915-919.[12] Xu J C,Xin P H,Xin Y Q,et al. Magnetic Properties and Methylene Blue Adsorptive Performance of CoFe2O4/Activated Carbon Nanocomposites[J]. Mater Chem Phys,2014,147(3):915-919.

    13. [13] Peng L,Qin P F,Lei M,et al. Modifying Fe3O4 Nanoparticles with Humic Acid for Removal of Rhodamine B in Water[J]. J Hazard Mater,2012,(209/210):193-198.[13] Peng L,Qin P F,Lei M,et al. Modifying Fe3O4 Nanoparticles with Humic Acid for Removal of Rhodamine B in Water[J]. J Hazard Mater,2012,(209/210):193-198.

    14. [14] Zhang X,Zhan P Y,Wu Z,et al. Adsorption of Methylene Blue onto Humic Acid-Coated Fe3O4 Nanoparticles[J]. Colloid Surf A,2013,435:85-90.[14] Zhang X,Zhan P Y,Wu Z,et al. Adsorption of Methylene Blue onto Humic Acid-Coated Fe3O4 Nanoparticles[J]. Colloid Surf A,2013,435:85-90.

    15. [15] ZHANG Wei. Preparation and Properties Research of Ferrite Spinel Manganese Material[D]. Nanjing:Nanjing University of Science & Technology,2006(in Chinese).张伟. 尖晶石型铁酸锰材料制备及性能研究[D]. 南京:南京理工大学,2006.[15] ZHANG Wei. Preparation and Properties Research of Ferrite Spinel Manganese Material[D]. Nanjing:Nanjing University of Science & Technology,2006(in Chinese).张伟. 尖晶石型铁酸锰材料制备及性能研究[D]. 南京:南京理工大学,2006.

    16. [16] XUAN Lei. Preparation and Characterization of Spinel Ferrite Minerals[D]. Ji'nan:Ji'nan University,2011(in Chinese).宣雷. 尖晶石结构铁酸盐矿物的制备和表征[D]. 济南:济南大学,2011.[16] XUAN Lei. Preparation and Characterization of Spinel Ferrite Minerals[D]. Ji'nan:Ji'nan University,2011(in Chinese).宣雷. 尖晶石结构铁酸盐矿物的制备和表征[D]. 济南:济南大学,2011.

    17. [17] Erzsébet Illés,Etelka Tombácz. The Role of Variable Surface Charge and Surface Complexation in the Adsorption of Humic Acid on Magnetite[J]. Colloid Surf A,2003,230(1/2/3):99-109.[17] Erzsébet Illés,Etelka Tombácz. The Role of Variable Surface Charge and Surface Complexation in the Adsorption of Humic Acid on Magnetite[J]. Colloid Surf A,2003,230(1/2/3):99-109.

    18. [18] Mak Sou-Yee,Chen Dong-Hwang. Fast Adsorption of Methylene Blue on Polyacrylic Acid-Bound Iron Oxide Magnetic Nanoparticles[J]. Dyes Pigm,2004,61(1):93-98.[18] Mak Sou-Yee,Chen Dong-Hwang. Fast Adsorption of Methylene Blue on Polyacrylic Acid-Bound Iron Oxide Magnetic Nanoparticles[J]. Dyes Pigm,2004,61(1):93-98.

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  • 收稿日期:  2015-07-21
  • 网络出版日期:  2015-08-21
通讯作者: 陈斌, bchen63@163.com
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