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水合物反应液中水活度系数模型研究进展

张锦 ,  周诗岽 ,  卢国维 ,  严红玉 ,  赵永利

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引用本文: 张锦, 周诗岽, 卢国维, 严红玉, 赵永利. 水合物反应液中水活度系数模型研究进展[J]. 应用化学, 2016, 33(3): 277-283. doi: 10.11944/j.issn.1000-0518.2016.03.150213 shu
Citation:  ZHANG Jin, ZHOU Shidong, LU Guowei, YAN Hongyu, ZHAO Yongli. Research Development of Activity Coefficient Models in Hydrate Reaction Media[J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 277-283. doi: 10.11944/j.issn.1000-0518.2016.03.150213 shu

水合物反应液中水活度系数模型研究进展

  • 1.

    常州大学油气储运技术省重点实验室 江苏 常州 213016

    • 通讯作者: 周诗岽,副教授;Tel/Fax:0519-83290280;E-mail:zsd@cczu.edu.cn;研究方向:天然气水化物技术
  • 基金项目:

    国家自然科学基金（51176015) 

    常州市工业支撑项目（CE20140055) 

    常州大学大学生科技创新基金项目（201504A17） 

摘要: 水合物反应液中水活度系数的计算对水合物相平衡特性的研究及水合物技术的应用具有重要意义。通过调研大量的国内外资料，概括了Margules、Wilson、NRTL、UNIQUAC及UNIFAC活度系数方程及其关联式等模型及其应用，结果表明，Margules模型常用于二元体系活度系数的计算，但对高温高压体系条件下的溶液适用性较差；Wilson模型参数回归误差稍大且不适于溶质与离子不能完全互溶体系；UNIQUAC模型在含水或咪唑类离子反应液体系中误差较大；多元离子体系相平衡的研究中常选择NRTL模型；UNIFAC模型拟合效果较好，可实现较高浓度体系活度系数的精确计算，应用较广泛。水活度关联方程参数拟合效果好，且准确度高，但在高温高压水合物反应液体系中的计算仍是一个技术难点，是今后的研究方向。

English

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  • 收稿日期:  2015-06-24
  • 网络出版日期:  2015-08-13
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