Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH3COO)2Co7(OH)2] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

Citation: LI Sa-Ying. Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand[J]. Chinese Journal of Structural Chemistry, 2016, 35(6): 980-986. doi: 10.14102/j.cnki.0254-5861.2011-0976 shu

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

LI Sa-Ying

1.
Department of Chemistry Chemical Engineering, Shaanxi Xueqian Normal University, Xi'an 710100, China
基金项目:
Project supported by College Programs SNIE (No. 2014ZDKJ011) (No. 2014ZDKJ011)

摘要: A new 3D cobalt metal-organic framework [C₇H₁₃N₂]₂[(CH₃COO)₂Co₇(oba)₅- (Hoba)₂(OH)₂]·H₂O has been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, XRD, and TG. This complex crystallizes in monoclinic system, space group P2₁/c with a = 19.4499(4), b = 10.8839(2), c = 27.7796(5) Å, β = 104.467(2)°, V = 5694.22(19) Å³, Z = 2, C₁₁₆H₉₂Co₇N₄O₄₂, M_r = 2626.45, D_c = 1.532 g/cm³, F(000) = 2682, μ = 1.085 mm^-1, R = 0.0387 and wR = 0.1177. Its structure is characterized as a 3D open framework constructed by seven nuclear clusters [(CH₃COO)₂Co₇(OH)₂] and the 4,4'-oxybisbenzoic acid ligand. The used ILs cations are located in the middle of the pore and compensate for the negative charges of framework. Furthermore, its fluorescence property has also been studied.

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

English

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

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