Syntheses, Structures and Properties <i>of Two Mn(II) Clusters Based on</i> <i>1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand</i>

Citation: MIAO Yan-Li, WANG Hong-Bo, GU Chang-Sheng, LI Yong. Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand[J]. Chinese Journal of Structural Chemistry, 2016, 35(6): 973-979. doi: 10.14102/j.cnki.0254-5861.2011-0966 shu

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

a.
a. College of Science, Guangdong Ocean University, Zhanjiang 524088, China;
b.
b. School of Navigation, Wuhan University of Technology, Wuhan 430063, China
基金项目:
This work was supported by Guangdong Ocean University with doctor start-up fund (1112263) (1112263)

Technology Plan Projects of Zhanjiang City (No. 2013B01073) (No. 2013B01073)

摘要: Two novel clusters [Mn^III₃(m₃-O)(phendox)₃]X·13H₂O (X = Cl (1), Br (2]) have been obtained from the solvothermal reactions of 1,10-phenanthroline-2,9-dicarbaldehyde dioxime (H₂phendox) with MnCl₂·4H₂O or anhydrous MnBr₂, and their structures were characterized by elemental analysis, FT-IR, XRD, TGA, MS and single-crystal X-ray diffraction. It crystallizes in trigonal, space group P3₁/c. X-ray analysis reveals that the neighbouring [Mn₃(m₃-O)(phendox)₃]⁺ cores are linked by C–H…Cl hydrogen bonds and form an infinite supramolecular chain along the c-axis. Neighbouring chains are packed with each other by off-set p-p interactions of the aromatic rings on phenox^2-. A 3D supramolecular architecture in a honeycomb topology is formed with 1D hexagonal channel in the dimensions of 13Å × 13Å along the c-axis. The gas adsorption studies show that compound 1·13H₂O is stable upon the removal of guest molecules and the desolvated compound absorbed considerable amount of CO₂.

关键词:

clusters
/ 1,10-phenanthroline-2,9-dicarbaldehyde dioxime
/ crystal structure
/ gas adsorption

English

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

a.
a. College of Science, Guangdong Ocean University, Zhanjiang 524088, China;
b.
b. School of Navigation, Wuhan University of Technology, Wuhan 430063, China
Received Date: 02 September 2015
Fund Project:

Abstract: Two novel clusters [Mn^III₃(m₃-O)(phendox)₃]X·13H₂O (X = Cl (1), Br (2]) have been obtained from the solvothermal reactions of 1,10-phenanthroline-2,9-dicarbaldehyde dioxime (H₂phendox) with MnCl₂·4H₂O or anhydrous MnBr₂, and their structures were characterized by elemental analysis, FT-IR, XRD, TGA, MS and single-crystal X-ray diffraction. It crystallizes in trigonal, space group P3₁/c. X-ray analysis reveals that the neighbouring [Mn₃(m₃-O)(phendox)₃]⁺ cores are linked by C–H…Cl hydrogen bonds and form an infinite supramolecular chain along the c-axis. Neighbouring chains are packed with each other by off-set p-p interactions of the aromatic rings on phenox^2-. A 3D supramolecular architecture in a honeycomb topology is formed with 1D hexagonal channel in the dimensions of 13Å × 13Å along the c-axis. The gas adsorption studies show that compound 1·13H₂O is stable upon the removal of guest molecules and the desolvated compound absorbed considerable amount of CO₂.

Key words:

clusters
/ 1,10-phenanthroline-2,9-dicarbaldehyde dioxime
/ crystal structure
/ gas adsorption

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

English

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

English

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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