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Syntheses and Structural Characterization of Multi-component Chalcogenide Compounds Based on Pyridine/1,2-Ethanedithiol Solvent

LIU Fang ,  WULAN Gerile ,  DA Lima ,  BAO Yong-Sheng ,  BAIYIN Meng He

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Citation:  LIU Fang, WULAN Gerile, DA Lima, BAO Yong-Sheng, BAIYIN Meng He. Syntheses and Structural Characterization of Multi-component Chalcogenide Compounds Based on Pyridine/1,2-Ethanedithiol Solvent[J]. Chinese Journal of Structural Chemistry, 2016, 35(6): 946-952. doi: 10.14102/j.cnki.0254-5861.2011-0963 shu

Syntheses and Structural Characterization of Multi-component Chalcogenide Compounds Based on Pyridine/1,2-Ethanedithiol Solvent

  • a.

    a. College of Chemistry & Environmental Science, Innner Mongolia Normal University, Hohhot 010022, China;

  • b.

    b. Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia, Hohhot 010022, China;

  • c.

    c. Chemistry and Chemical Engineering College, Inner Mongolia University for the Nationalities, Tongliao 028043, China

  • 基金项目:

    This project was supported by the National Natural Science Foundation of China (No.21461019) (No.21461019)

摘要: Reactions of Sn powder, cadmium iodide, rubidium carbonate, and sodium sulfide yielded two new compounds: three-dimensional chalcogenide RbNa3Cd2Sn2S8 (1) and layered ternary compound Na2CdS2 (2). 1 and 2 have been determined by single-crystal X-ray diffraction: 1 belongs to the orthorhombic space group Pca21, with a = 13.486(3), b = 6.7310(14), c = 18.401(4) Å and Z = 4; 2 crystallizes in the R3m space group, with a = 3.718(3), c = 26.170(4) Å and Z = 3. Study of the yellow block shaped crystals of 1 reveals that the structure consists of tetrahedral CdS4 and SnS4. The {Cd2Sn2S8} cluster shows a 12-numbered ring structure assembled by corner-sharing of alternating SnS4 and CdS4, and the rubidium and sodium ions act as void-filling and charge compensating cations. The dark orange hexagonal crystal of compound 2 consists of a unique [CdS2]2- layer, which are separated by the Na+. UV/Vis absorption spectrum exhibits the materials 1 and 2 have semiconductor properties.

English

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