Crystal Structures and Photoluminescent Properties of Two Cd<sup>2+</sup> Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

Citation: JIN Suo, GU Qing-Yun, CHEN Jing, WANG Yang-Zhi, YUAN Guo-Zan. Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand[J]. Chinese Journal of Structural Chemistry, 2016, 35(6): 929-938. doi: 10.14102/j.cnki.0254-5861.2011-0984 shu

Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

a.
a. School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, China;
b.
b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
基金项目:
This work was supported by the National Natural Science Foundation of China (No. 21201002) (No. 21201002)

the Foundation of State Key Laboratory of Structural Chemistry (20130016) (20130016)

Anhui Provincial Natural Science Foundation (1308085QB22) (1308085QB22)

摘要: In order to perform a study on the structural modulation in the Cd(II)-L architecture (HL = (E)-2-[2-(3-pyridyl)ethenyl]-8-hydroxyquinoline), two different dicarboxylic acids, namely, 2-aminoterephthalic acid (H₂ATA) and 4,4'-biphenyldicarboxylic acid (H₂BPDC), are employed as the secondary auxiliary ligands. Two new complexes [Cd₂L₂(ATA)] (1) and [Cd₂L₂(BPDC)·2MeOH· 4H₂O] (2) with distinct 3D frameworks were obtained. In complex 1, ligands ATA bridge the 1D Cd(II)-L infinite chains into a 3D polymeric coordination network. Complex 2 is a 3D porous framework, in which adjacent 2D Cd(II)-L coordination layers were linked together by the coor- dinated BPDC ligands. The variant structures of two complexes indicate that the skeleton of dicarboxylate anions plays a great role in the assembly of such different frameworks. In addition, the photoluminescent properties (fluorescent emission, lifetime, and quantum yield) of polymers 1 and 2 were also investigated in the solid state.

关键词:

English

Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

a.
a. School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, China;
b.
b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
Received Date: 24 September 2015
Fund Project:

Abstract: In order to perform a study on the structural modulation in the Cd(II)-L architecture (HL = (E)-2-[2-(3-pyridyl)ethenyl]-8-hydroxyquinoline), two different dicarboxylic acids, namely, 2-aminoterephthalic acid (H₂ATA) and 4,4'-biphenyldicarboxylic acid (H₂BPDC), are employed as the secondary auxiliary ligands. Two new complexes [Cd₂L₂(ATA)] (1) and [Cd₂L₂(BPDC)·2MeOH· 4H₂O] (2) with distinct 3D frameworks were obtained. In complex 1, ligands ATA bridge the 1D Cd(II)-L infinite chains into a 3D polymeric coordination network. Complex 2 is a 3D porous framework, in which adjacent 2D Cd(II)-L coordination layers were linked together by the coor- dinated BPDC ligands. The variant structures of two complexes indicate that the skeleton of dicarboxylate anions plays a great role in the assembly of such different frameworks. In addition, the photoluminescent properties (fluorescent emission, lifetime, and quantum yield) of polymers 1 and 2 were also investigated in the solid state.

Key words:

1. [1]
  (1) Eliseeva, S. V.; Bünzli, J. C. G. Lanthanide luminescence for functional materials and bio-sciences. Chem. Soc. Rev. 2010, 39, 189-227.(1) Eliseeva, S. V.; Bünzli, J. C. G. Lanthanide luminescence for functional materials and bio-sciences. Chem. Soc. Rev. 2010, 39, 189-227.
2. [2]
  (2) Binnemans, K. Lanthanide-based luminescent hybrid materials. Chem. Rev. 2009, 109, 4283-4374.(2) Binnemans, K. Lanthanide-based luminescent hybrid materials. Chem. Rev. 2009, 109, 4283-4374.
3. [3]
  (3) Hwang, S. H.; Moorefield, C. N.; Newkome, G. R. Dendritic macromolecules for organic light-emitting diodes. Chem. Soc. Rev. 2008, 37, 2543-2557.(3) Hwang, S. H.; Moorefield, C. N.; Newkome, G. R. Dendritic macromolecules for organic light-emitting diodes. Chem. Soc. Rev. 2008, 37, 2543-2557.
4. [4]
  (4) Carlos, L. D.; Ferreira, R. A. S.; de Zea Bermudez, V.; Julián-López, B.; Escribano, P. Progress on lanthanide-based organic-inorganic hybrid phosphors. Chem. Soc. Rev. 2011, 40, 536-549.(4) Carlos, L. D.; Ferreira, R. A. S.; de Zea Bermudez, V.; Julián-López, B.; Escribano, P. Progress on lanthanide-based organic-inorganic hybrid phosphors. Chem. Soc. Rev. 2011, 40, 536-549.
5. [5]
  (5) Suh, M.; Cheon, Y.; Lee, E. Syntheses and functions of porous metallo supramolecular networks. Coord. Chem. Rev. 2008, 252, 1007-1026.(5) Suh, M.; Cheon, Y.; Lee, E. Syntheses and functions of porous metallo supramolecular networks. Coord. Chem. Rev. 2008, 252, 1007-1026.
6. [6]
  (6) Maspoch, D.; Ruiz-Molina, D.; Veciana, J. Old materials with new tricks: multifunctional open-framework materials. Chem. Soc. Rev. 2007, 36, 770-818.(6) Maspoch, D.; Ruiz-Molina, D.; Veciana, J. Old materials with new tricks: multifunctional open-framework materials. Chem. Soc. Rev. 2007, 36, 770-818.
7. [7]
  (7) Rocha, J.; Carlos, L. D.; Paz, F. A. A.; Ananias, D. Luminescent multifunctional lanthanids based metal–organic frameworks. Chem. Soc. Rev. 2011, 40, 926-940.(7) Rocha, J.; Carlos, L. D.; Paz, F. A. A.; Ananias, D. Luminescent multifunctional lanthanids based metal–organic frameworks. Chem. Soc. Rev. 2011, 40, 926-940.
8. [8]
  (8) Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Luminescent metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1330-1352.(8) Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Luminescent metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1330-1352.
9. [9]
  (9) Chen, B.; Xiang, S.; Qian, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115-1124.(9) Chen, B.; Xiang, S.; Qian, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115-1124.
10. [10]
  (10) Shekhah, O.; Liu, J.; Fischerand, R. A.; Wöll, C. MOF thin films: existing and future applications. Chem. Soc. Rev. 2011, 40, 1081-1106.(10) Shekhah, O.; Liu, J.; Fischerand, R. A.; Wöll, C. MOF thin films: existing and future applications. Chem. Soc. Rev. 2011, 40, 1081-1106.
11. [11]
  (11) Yang, X.; Jones, R. A.; Huang, S. Luminescent 4f and d-4f polynuclear complexes and coordination polymers with flexible salen-type ligands. Coord. Chem. Rev. 2014, 273, 63-75.(11) Yang, X.; Jones, R. A.; Huang, S. Luminescent 4f and d-4f polynuclear complexes and coordination polymers with flexible salen-type ligands. Coord. Chem. Rev. 2014, 273, 63-75.
12. [12]
  (12) Cui, Y.; Chen, B.; Qian, G. Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications. Coord. Chem. Rev. 2014, 273, 76-86.(12) Cui, Y.; Chen, B.; Qian, G. Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications. Coord. Chem. Rev. 2014, 273, 76-86.
13. [13]
  (13) Zhou, Y.; Li, X.; Zhang, L.; Guo, Y.; Shi, Z. 3-D silver(i)-lanthanide(iii) heterometallic organic frameworks constructed from 2,2'-bipyridine-3,3'-dicarboxylic acid: synthesis, structure, photoluminescence, and their remarkable thermostability. Inorg. Chem. 2014, 53, 3362-3370.(13) Zhou, Y.; Li, X.; Zhang, L.; Guo, Y.; Shi, Z. 3-D silver(i)-lanthanide(iii) heterometallic organic frameworks constructed from 2,2'-bipyridine-3,3'-dicarboxylic acid: synthesis, structure, photoluminescence, and their remarkable thermostability. Inorg. Chem. 2014, 53, 3362-3370.
14. [14]
  (14) Qin, J. S.; Bao, S. J.; Li, P.; Xie, W.; Du, D. Y.; Zhao, L.; Lan, Y. Q.; Su, Z. M. A. Stable porous anionic metal-organic framework for luminescence sensing of ln³⁺ ions action of nitrobenzene. Chem. Asian J. 2014, 9, 749-753.(14) Qin, J. S.; Bao, S. J.; Li, P.; Xie, W.; Du, D. Y.; Zhao, L.; Lan, Y. Q.; Su, Z. M. A. Stable porous anionic metal-organic framework for luminescence sensing of ln³⁺ ions action of nitrobenzene. Chem. Asian J. 2014, 9, 749-753.
15. [15]
  (15) Wen, L.; Li, Y.; Lu, Z.; Lin, J.; Meng, C. D. Syntheses and structures of four d¹⁰ metal-organic frameworks assembled with aromatic polycarboxylate and bix (bix = 1,4-bis(imidazol-1-ylmethyl)benzene). Cryst. Growth Des. 2006, 6, 530-537.(15) Wen, L.; Li, Y.; Lu, Z.; Lin, J.; Meng, C. D. Syntheses and structures of four d¹⁰ metal-organic frameworks assembled with aromatic polycarboxylate and bix (bix = 1,4-bis(imidazol-1-ylmethyl)benzene). Cryst. Growth Des. 2006, 6, 530-537.
16. [16]
  (16) Bauer, C. A.; Timofeeva, T. V.; Settersten, T. B.; Patterson, B. D.; Liu, V. H.; Simmons, B. A.; Allendorf, M. D. Influence of connectivity and porosity on ligand-based luminescence in zinc metal-organic frameworks. J. Am. Chem. Soc. 2007, 129, 7136-7144.(16) Bauer, C. A.; Timofeeva, T. V.; Settersten, T. B.; Patterson, B. D.; Liu, V. H.; Simmons, B. A.; Allendorf, M. D. Influence of connectivity and porosity on ligand-based luminescence in zinc metal-organic frameworks. J. Am. Chem. Soc. 2007, 129, 7136-7144.
17. [17]
  (17) Wu, H. C.; Thanasekaran, P.; Tsai, C. H.; Wu, J. Y.; Huang, S. M.; Wen, Y. S.; Lu, K. L. Self-assembly, reorganization, and photophysical properties of silver(i)-Schiff-base molecular rectangle and polymeric array species. Inorg. Chem. 2006, 45, 295-303.(17) Wu, H. C.; Thanasekaran, P.; Tsai, C. H.; Wu, J. Y.; Huang, S. M.; Wen, Y. S.; Lu, K. L. Self-assembly, reorganization, and photophysical properties of silver(i)-Schiff-base molecular rectangle and polymeric array species. Inorg. Chem. 2006, 45, 295-303.
18. [18]
  (18) Shustova, N. B.; Cozzolino, A. F.; Dinca, M. Conformational locking by design: relating strain energy with luminescence and stability in rigid metal–organic frameworks. J. Am. Chem. Soc. 2012, 134, 19596-19599.(18) Shustova, N. B.; Cozzolino, A. F.; Dinca, M. Conformational locking by design: relating strain energy with luminescence and stability in rigid metal–organic frameworks. J. Am. Chem. Soc. 2012, 134, 19596-19599.
19. [19]
  (19) Cui, Y.; Yue, Y.; Qian, G.; Chen, B. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 1126-1162.(19) Cui, Y.; Yue, Y.; Qian, G.; Chen, B. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 1126-1162.
20. [20]
  (20) Zhang, M. D.; Qin, L.; Yang, H. T.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Series of metal-organic frameworks including novel architectural features based on a star-like tri(4-pyridylphenyl)amine ligand. Cryst. Growth Des. 2013, 13, 1961-1969.(20) Zhang, M. D.; Qin, L.; Yang, H. T.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Series of metal-organic frameworks including novel architectural features based on a star-like tri(4-pyridylphenyl)amine ligand. Cryst. Growth Des. 2013, 13, 1961-1969.
21. [21]
  (21) Tang, C. W.; VanSlyke, S. A. Organic electroluminescent diodes. Appl. Phys. Lett. 1987, 51, 913-915.(21) Tang, C. W.; VanSlyke, S. A. Organic electroluminescent diodes. Appl. Phys. Lett. 1987, 51, 913-915.
22. [22]
  (22) Brinkmann, M.; Gadret, G.; Muccini, M.; Taliani, C.; Masciocchi, N.; Sironi, A. Correlation between molecular packing and optical properties indifferent crystalline polymorphs and amorphous thin films of mer-tris(8-hydroxyquinoline)aluminum(III). J. Am. Chem. Soc. 2000, 122, 5147-5157.(22) Brinkmann, M.; Gadret, G.; Muccini, M.; Taliani, C.; Masciocchi, N.; Sironi, A. Correlation between molecular packing and optical properties indifferent crystalline polymorphs and amorphous thin films of mer-tris(8-hydroxyquinoline)aluminum(III). J. Am. Chem. Soc. 2000, 122, 5147-5157.
23. [23]
  (23) Cöle, M.; Dinnebier, R. E.; Brütting, W. The structure of the blue luminescent δ-phase of tris(8-hydroxyquinoline)aluminium(III) (Alq₃). Chem. Commun. 2002, 23, 2908-2909.(23) Cöle, M.; Dinnebier, R. E.; Brütting, W. The structure of the blue luminescent δ-phase of tris(8-hydroxyquinoline)aluminium(III) (Alq₃). Chem. Commun. 2002, 23, 2908-2909.
24. [24]
  (24) Bi, H.; Zhang, H.; Zhang, Y.; Gao, H.; Su, Z.; Wang, Y. Fac-alq(3) and mer-alq(3) nano/microcrystals with different emission and charge-transporting properties. Adv. Mater. 2010, 22, 1631-1634.(24) Bi, H.; Zhang, H.; Zhang, Y.; Gao, H.; Su, Z.; Wang, Y. Fac-alq(3) and mer-alq(3) nano/microcrystals with different emission and charge-transporting properties. Adv. Mater. 2010, 22, 1631-1634.
25. [25]
  (25) Kulkarni, A. P.; Tonzola, C. J.; Babel, A.; Jenekhe, S. A. Electron transport materials for organic light-emitting diodes. Chem. Mater. 2004, 16, 4556-4573.(25) Kulkarni, A. P.; Tonzola, C. J.; Babel, A.; Jenekhe, S. A. Electron transport materials for organic light-emitting diodes. Chem. Mater. 2004, 16, 4556-4573.
26. [26]
  (26) Pérez-Bolívar, C.; Takizawa, S.; Nishimura, G.; Montes, V. A.; Anzenbacher, P. High-efficiency tris(8-hydroxyquinoline)aluminum(III) (Alq₃) complexes for organic white-light- emittigdiodes and solid-state lighting. Chem. Eur. J. 2011, 17, 9076-9082.(26) Pérez-Bolívar, C.; Takizawa, S.; Nishimura, G.; Montes, V. A.; Anzenbacher, P. High-efficiency tris(8-hydroxyquinoline)aluminum(III) (Alq₃) complexes for organic white-light- emittigdiodes and solid-state lighting. Chem. Eur. J. 2011, 17, 9076-9082.
27. [27]
  (27) Yuan, G. Z.; Shan, W. L.; Qiao, X. L.; M, L.; Huo, Y. P. Self-assembly of five 8-hydroxyquinolinate-based complexes: tunable core, supramolecular structure, and photoluminescence properties. Chem. Asian. J. 2014, 9, 1913-1921.(27) Yuan, G. Z.; Shan, W. L.; Qiao, X. L.; M, L.; Huo, Y. P. Self-assembly of five 8-hydroxyquinolinate-based complexes: tunable core, supramolecular structure, and photoluminescence properties. Chem. Asian. J. 2014, 9, 1913-1921.
28. [28]
  (28) Yuan, G.; Huo, Y.; Nie, X.; Fang, X.; Zhu, S. Structure and photophysical properties of adimeric Zn(II) complex based on 8-hydroxyquinoline group containing 2,6-dichlorobenzene unit. Tetrahedron 2012, 68, 8018-8023.(28) Yuan, G.; Huo, Y.; Nie, X.; Fang, X.; Zhu, S. Structure and photophysical properties of adimeric Zn(II) complex based on 8-hydroxyquinoline group containing 2,6-dichlorobenzene unit. Tetrahedron 2012, 68, 8018-8023.
29. [29]
  (29) Yuan, G.; Huo, Y.; Rong, L.; Nie, X.; Fang. X. Photoluminescences and 3D supramolecular structure with unique dimeric Zn(II) units featuring 2-substituted 8-hydroxyquinoline. Inorg. Chem. Commun. 2012, 23, 90-94.(29) Yuan, G.; Huo, Y.; Rong, L.; Nie, X.; Fang. X. Photoluminescences and 3D supramolecular structure with unique dimeric Zn(II) units featuring 2-substituted 8-hydroxyquinoline. Inorg. Chem. Commun. 2012, 23, 90-94.
30. [30]
  (30) Yuan, G.; Huo, Y.; Nie, X.; Jiang, H.; Liu, B.; Fang, X.; Zhao. F. Controllable supramolecular structures and luminescent properties of unique trimeric Zn(II) 8-hydroxyquinolinates tuned by functional substituents. Dalton Trans. 2013, 42, 2921-2929.(30) Yuan, G.; Huo, Y.; Nie, X.; Jiang, H.; Liu, B.; Fang, X.; Zhao. F. Controllable supramolecular structures and luminescent properties of unique trimeric Zn(II) 8-hydroxyquinolinates tuned by functional substituents. Dalton Trans. 2013, 42, 2921-2929.
31. [31]
  (31) Sokołowski, K.; Justyniak, I.; Śliwiński, W.; Sołtys, K.; Tulewicz, A.; Kornowicz, A.; Moszyński, R.; Lipkowski, J.; Lewiński, J. Towards a new family of photoluminescent organozinc 8-hydroxyquinolinates with a high propensity to form noncovalent porous materials. Chem. Eur. J. 2012, 18, 5637-5645.(31) Sokołowski, K.; Justyniak, I.; Śliwiński, W.; Sołtys, K.; Tulewicz, A.; Kornowicz, A.; Moszyński, R.; Lipkowski, J.; Lewiński, J. Towards a new family of photoluminescent organozinc 8-hydroxyquinolinates with a high propensity to form noncovalent porous materials. Chem. Eur. J. 2012, 18, 5637-5645.
32. [32]
  (32) Zhang, L.; Rong, L.; Hu, G.; Jin, S.; Jia, W.; Liu, J.; Yuan, G. Six Zn(II) and Cd(II) coordination polymers assembled from a similar binuclear building unit: tunable structures and luminescence properties. Dalton Trans. 2015, 44, 6731-6739.(32) Zhang, L.; Rong, L.; Hu, G.; Jin, S.; Jia, W.; Liu, J.; Yuan, G. Six Zn(II) and Cd(II) coordination polymers assembled from a similar binuclear building unit: tunable structures and luminescence properties. Dalton Trans. 2015, 44, 6731-6739.
33. [33]
  (33) Zhang, M. D.; Qin, L.; Yang, H. T.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Series of metal-organic frameworks including novel architectural features based on a star-like tri(4-pyridylphenyl)amine ligand. Cryst. Growth. Des. 2013, 13, 1961-1969.(33) Zhang, M. D.; Qin, L.; Yang, H. T.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Series of metal-organic frameworks including novel architectural features based on a star-like tri(4-pyridylphenyl)amine ligand. Cryst. Growth. Des. 2013, 13, 1961-1969.
34. [34]
  (34) Zhou, X.; Fang, H.; Ge, Y.; Zhou, Z.; Gu, Z.; Gong, X.; Zhao, G.; Zhan, Q.; Zeng, R.; Cai, Y. Assembly of a series of trinuclear zinc(II) compounds with N₂O₂ donor tetradentat esymmetrical schiff base ligand. Cryst. Growth. Des. 2010, 10, 4014-4022.(34) Zhou, X.; Fang, H.; Ge, Y.; Zhou, Z.; Gu, Z.; Gong, X.; Zhao, G.; Zhan, Q.; Zeng, R.; Cai, Y. Assembly of a series of trinuclear zinc(II) compounds with N₂O₂ donor tetradentat esymmetrical schiff base ligand. Cryst. Growth. Des. 2010, 10, 4014-4022.
35. [35]
  (35) Perkovic, M. W. Allosteric manipulation of photoexcited state relaxation in (bpy)₂ruⁱⁱ(binicotinicacid). Inorg. Chem. 2000, 39, 4962-4968.(35) Perkovic, M. W. Allosteric manipulation of photoexcited state relaxation in (bpy)₂ruⁱⁱ(binicotinicacid). Inorg. Chem. 2000, 39, 4962-4968.
36. [36]
  (36) Huo, Y.; Zhu, S.; Hu, S. Synthesis and luminescent properties of Zn complex based on 8-hydroxyquinoline group containing 3,5-bis(trifluoromethyl)benzene unit with unique crystal structure. Tetrahedron 2010, 66, 8635-8640.(36) Huo, Y.; Zhu, S.; Hu, S. Synthesis and luminescent properties of Zn complex based on 8-hydroxyquinoline group containing 3,5-bis(trifluoromethyl)benzene unit with unique crystal structure. Tetrahedron 2010, 66, 8635-8640.
37. [37]
  (37) Selmarten, D.; Jones, M.; Rumbles, G.; Yu, P.; Nedeljkovicand, J.; Shaheen, S. Quenching of seiconductor quantum dot photoluminescence by apiconjugated polymer. J. Phys. Chem. B 2005 , 9, 15927-15932.(37) Selmarten, D.; Jones, M.; Rumbles, G.; Yu, P.; Nedeljkovicand, J.; Shaheen, S. Quenching of seiconductor quantum dot photoluminescence by apiconjugated polymer. J. Phys. Chem. B 2005 , 9, 15927-15932.
38. [38]
  (38) Li , Y. W.; Ma, H.; Chen, Y. Q.; He, K. H.; Li, Z. X; Bu, X. H. Structure modulation in Zn(II)-1,4-bis(imidazol-1-yl)benzene frameworks by varying dicarboxylate anions. Cryst. Growth Des. 2012, 12, 189-196.(38) Li , Y. W.; Ma, H.; Chen, Y. Q.; He, K. H.; Li, Z. X; Bu, X. H. Structure modulation in Zn(II)-1,4-bis(imidazol-1-yl)benzene frameworks by varying dicarboxylate anions. Cryst. Growth Des. 2012, 12, 189-196.

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Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

English

Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

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中国化学会秘书处

Crystal Structures and Photoluminescent Properties of Two Cd2+ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

English

Crystal Structures and Photoluminescent Properties of Two Cd2+ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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中国化学会秘书处

Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs