Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO2-BDC)(4,4'-DPA)]·(DMF)}n

Citation: LIU Ying, WANG Yu-Ling, CHEN Ling, LIU Qing-Yan, YAO Yang. Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n[J]. Chinese Journal of Structural Chemistry, 2016, 35(6): 921-928. doi: 10.14102/j.cnki.0254-5861.2011-0974 shu

Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n

1.
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
基金项目:

the Natural Science Foundation of Jiangxi Province (No. 20151BAB203002) (No. 20151BAB203002)

摘要: The reaction of Cd(NO₃)₂·4H₂O with 4,4'-dipyridylacetylene (4,4'-DPA) and 2-nitroterephthalic acid (2-NO₂-H₂BDC) in DMF/H₂O mixed solvent has afforded a compound {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n (1). Compound 1 has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetry analysis, and IR spectrum. Com- pound 1 crystallizes in the monoclinic system, space group P2₁/n, with a = 12.1488(3), b = 14.6689(3), c = 13.1615(3) Å, β = 111.809(3)^o, V = 2177.63(9) Å³, Z = 4, C₂₃H₁₈ N₄O₇Cd, M_r= 574.81, D_c= 1.753 g/cm³, μ = 8.523 mm^-1, F(000) = 1152, the final R = 0.0411 and wR = 0.1064 for 3589 observed reflections with I > 2s(I). In compound 1, the Cd(II) ions are linked by the carboxylate groups of 2-NO₂-BDC ligands to give a two-dimensional layered structure based on the centrosymmetric dinuclear Cd₂(COO)₂ units, which are further connected by the 4,4'-DPA ligands to produce a three-dimensional framework with pcu topology. Careful examination revealed that compound 1 is a 2-fold interpenetrating framework. Furthermore, the gas adsorption properties of 1 for N₂ and CO₂ have also been investigated.

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English

Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n

1.
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
Received Date: 15 September 2015

Abstract: The reaction of Cd(NO₃)₂·4H₂O with 4,4'-dipyridylacetylene (4,4'-DPA) and 2-nitroterephthalic acid (2-NO₂-H₂BDC) in DMF/H₂O mixed solvent has afforded a compound {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n (1). Compound 1 has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetry analysis, and IR spectrum. Com- pound 1 crystallizes in the monoclinic system, space group P2₁/n, with a = 12.1488(3), b = 14.6689(3), c = 13.1615(3) Å, β = 111.809(3)^o, V = 2177.63(9) Å³, Z = 4, C₂₃H₁₈ N₄O₇Cd, M_r= 574.81, D_c= 1.753 g/cm³, μ = 8.523 mm^-1, F(000) = 1152, the final R = 0.0411 and wR = 0.1064 for 3589 observed reflections with I > 2s(I). In compound 1, the Cd(II) ions are linked by the carboxylate groups of 2-NO₂-BDC ligands to give a two-dimensional layered structure based on the centrosymmetric dinuclear Cd₂(COO)₂ units, which are further connected by the 4,4'-DPA ligands to produce a three-dimensional framework with pcu topology. Careful examination revealed that compound 1 is a 2-fold interpenetrating framework. Furthermore, the gas adsorption properties of 1 for N₂ and CO₂ have also been investigated.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n

English

Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n

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