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季铵盐改性氧化石墨烯的制备及其性能研究

惠昱晨 ,  马晓燕 ,  陈智群 ,  张皋 ,  宋颖 ,  侯秀璋

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引用本文: 惠昱晨, 马晓燕, 陈智群, 张皋, 宋颖, 侯秀璋. 季铵盐改性氧化石墨烯的制备及其性能研究[J]. 无机化学学报, 2013, 29(5): 922-928. doi: 10.3969/j.issn.1001-4861.2013.00.084 shu
Citation:  HUI Yu-Chen, MA Xiao-Yan, CHEN Zhi-Qun, ZHANG Gao, SONG Ying, HOU Xiu-Zhang. Preparation of Quaternary Ammonium Salt Modified Graphene Oxide and Its Properties[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(5): 922-928. doi: 10.3969/j.issn.1001-4861.2013.00.084 shu

季铵盐改性氧化石墨烯的制备及其性能研究

    通讯作者: 马晓燕,E-mail:m_xiao_yana@nwpu.edu.cn,Tel:(029)88431676;会员登记号:S06N9290M1007,
  • 基金项目:

    陕西省自然科学研究计划重点项目(No.2009JZ004)资助项目。 (No.2009JZ004)

摘要: 本论文采用改进的Hummers法制备了氧化石墨烯(GO),并将氧化石墨烯用十二烷基二甲基苄基氯化铵(1227)进行修饰,得到1227非共价改性的氧化石墨烯(GO-1227)。用拉曼光谱、漫反射红外光谱分析、X-射线光电子表面能谱技术表征了其化学结构;用X-射线衍射分析、扫描电子显微镜与透射电子显微镜观察了其剥离情况和微观形貌;分析了它们在不同溶剂中的分散性。结果表明,季铵盐改性后,1227阳离子通过静电作用插入到GO片层之间,使GO片层进一步剥离,且在极性较弱的有机溶剂中的溶解性增加。热失重分析表明,GO-1227的初始分解温度提高了约70 ℃。将GO-1227与聚甲基丙烯酸甲酯与苯乙烯的嵌段共聚物(PMMA-b-PS)凝胶聚电解质复合,制备了纳米复合凝胶聚合物电解质(NGPE),并用交流阻抗法测试其电性能,发现占聚电解质总质量2‰的GO-1227可以将其离子电导率提高8.6倍。

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  • 收稿日期:  2012-09-17
  • 网络出版日期:  2012-11-12
通讯作者: 陈斌, bchen63@163.com
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