引用本文:
吕正荣, 高松奇, 周耀坤, 吴绍祖. 环戊二烯基(或甲基环戊二烯基)钛(锆)三(二硫代N-环烷氨基甲酸盐)的合成和表征[J]. 应用化学,
1992, 9(3): 110-113.
Citation: Lü Zhengrong, Gao Songqi, Zhou Yaokun, Wu Shaozu. SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTADIENYL (OR METHYLCYCLOPENTADIENYL)TITANIUM (Ⅳ) ZIRCONIUM(Ⅳ) TRISDITHIOCARBAMATES[J]. Chinese Journal of Applied Chemistry, 1992, 9(3): 110-113.
Citation: Lü Zhengrong, Gao Songqi, Zhou Yaokun, Wu Shaozu. SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTADIENYL (OR METHYLCYCLOPENTADIENYL)TITANIUM (Ⅳ) ZIRCONIUM(Ⅳ) TRISDITHIOCARBAMATES[J]. Chinese Journal of Applied Chemistry, 1992, 9(3): 110-113.
环戊二烯基(或甲基环戊二烯基)钛(锆)三(二硫代N-环烷氨基甲酸盐)的合成和表征
English
SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTADIENYL (OR METHYLCYCLOPENTADIENYL)TITANIUM (Ⅳ) ZIRCONIUM(Ⅳ) TRISDITHIOCARBAMATES
Abstract:
Thirteen new compounds of type (RCp)M(S2CNR2)3 were synthesized by reacting (RCp)2MCl2(R=H, Me;M=Ti(Ⅳ), Zr(Ⅳ)) with sodium pyrrolidine-, piperidine- and morpholine-dithiocarbamates, respectively. The IR spectra showed that the dithiocarhamic ligands behave as bidentate ligands in the complexes. The 1H-NMR spectra showed that all complexes are rigid compounds.
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Key words:
- cyelopentadienyl
- / titanium
- / zirconium
- / dithiocarbamate
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