引用本文:
刘淑清, 孙浩然, 徐吉庆, 李冬梅. 四(4-N-吡啶基)卟啉衍生物的合成及表征[J]. 应用化学,
2000, 17(3): 260-263.
Citation: LIU Shu-Qing, SUN Hao-Ran, XU Ji-Qing, LI Dong-Mei. Synthesis and Characterization of Meso-Tetrakis (4-pyridyl)porphyrin Derivatives[J]. Chinese Journal of Applied Chemistry, 2000, 17(3): 260-263.
Citation: LIU Shu-Qing, SUN Hao-Ran, XU Ji-Qing, LI Dong-Mei. Synthesis and Characterization of Meso-Tetrakis (4-pyridyl)porphyrin Derivatives[J]. Chinese Journal of Applied Chemistry, 2000, 17(3): 260-263.
四(4-N-吡啶基)卟啉衍生物的合成及表征
English
Synthesis and Characterization of Meso-Tetrakis (4-pyridyl)porphyrin Derivatives
Abstract:
Four cationic meso-tetrakis(4-N-pyridyl)porphyrin derivatives 5,10,15,20 tetra kis (4-N-benzylpyridyl)porphyrin(H2TBPyP), 5,10,15,20-tetrakis(4-N-propylpyridyl)porphyrin(H2TPPyP), 5,10,15,20 tetrakis(4-N-ethylpyridyl)porphyrin(H2TEPyP), 5,10,15,20-tetrakis(4-N-methylpyridyl)porphyrin(H2TMPyP), and their cobalt complexes have been synthesized. Some of the porphyrin compounds were characterized by elemental analysis, matrix-assisted laser desorption/ionization time of flight-mass spectrometry(MALDI-TOF-MS), UV-Vis, FTIR, 1H NMR and cyclic voltammetry.
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Key words:
- cationic porphyrin
- / complex
- / synthesis
- / reductive potential
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