引用本文:
陈胜洲, 李焰, 陈祖兴. 酶促酮酸酯还原合成(S)-2-乙酰氧基十三烷[J]. 应用化学,
2002, 19(1): 85-87.
Citation: CHEN Sheng-Zhou, LI Yan, CHEN Zu-Xing. Synthesis of (S)-2-Acetoxyltridecane by Enzymatic Reduction of β-Ketoester[J]. Chinese Journal of Applied Chemistry, 2002, 19(1): 85-87.
Citation: CHEN Sheng-Zhou, LI Yan, CHEN Zu-Xing. Synthesis of (S)-2-Acetoxyltridecane by Enzymatic Reduction of β-Ketoester[J]. Chinese Journal of Applied Chemistry, 2002, 19(1): 85-87.
酶促酮酸酯还原合成(S)-2-乙酰氧基十三烷
摘要:
Bartelt等[1]于1989年首次从穆勒果蝇(Drosophila mulleric)的雄性成虫体内分离出其聚集信息素,并确证其主要生物活性的成分为(S)-构型的2-乙酰氧基十三烷(1),而(R)-构型无生物活性.
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关键词:
- (S)-乙酰氧基十三烷
- / 酶促还原反应
- / 合成
- / 信息素
English
Synthesis of (S)-2-Acetoxyltridecane by Enzymatic Reduction of β-Ketoester
Abstract:
(S)-2-Acetoxyltridecane, which is the aggregation pheromone of Drosophila Mulleric and the sex pheromone component of the pea midge (Contarinia pisi), was synthesized from ethyl acetoacetate by enzymatic reduction with baker's yeast in the presence of ethyl chloroacetate as a key step. The optical purity of the target product is about 98%e.e.
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Key words:
- (S)-acetoxyltridecane
- / enzymatic reduction
- / synthesis
- / pheromone
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