引用本文:
彭亦如, 陈耐生, 黄金陵, 林志鹏, 薛金萍. 四磺酸酞菁锌四钾盐的合成与表征[J]. 应用化学,
2002, 19(8): 730-733.
Citation: PENG Yi-Ru, CHEN Nai-Sheng, HUANG Jin-Ling, LIN Zhi-Peng, XUE Jin-Ping. Synthesis and Characterization of Tetra Potassium Salt of Zinc Tetra Sulfophthalocyanine[J]. Chinese Journal of Applied Chemistry, 2002, 19(8): 730-733.
Citation: PENG Yi-Ru, CHEN Nai-Sheng, HUANG Jin-Ling, LIN Zhi-Peng, XUE Jin-Ping. Synthesis and Characterization of Tetra Potassium Salt of Zinc Tetra Sulfophthalocyanine[J]. Chinese Journal of Applied Chemistry, 2002, 19(8): 730-733.
四磺酸酞菁锌四钾盐的合成与表征
摘要:
合成了酞菁配合物的2种"分子碎片":4-磺酸邻苯二甲酸单钾盐和4-磺酸邻苯二甲腈单钾盐。比较并讨论了以钼酸铵为催化剂,通过加热熔融和在惰性溶剂中反应的方法合成2,10,18,26-四磺酸酞菁锌四钾盐时,对目标产物的产率和异构体的影响。其中以4-磺酸邻苯二甲酸单钾盐为原料的产率可达46%,并对"分子碎片"和配合物进行了元素分析、IR、1H NMR以及13C NMR表征。
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关键词:
- 磺酸邻苯二甲酸单钾盐
- / 磺酸邻苯二甲腈单钾盐
- / 四磺酸酞菁锌四钾盐
- / 合成
English
Synthesis and Characterization of Tetra Potassium Salt of Zinc Tetra Sulfophthalocyanine
Abstract:
The monopatassium salt of 4-sulfophthalic acid and monopotassium salt of 4-sulfophthalonitrile were synthesized and condensed to give tetrapotassium salt of zinc tetra sulfophthalocyanine by the solid fusion method or reaction in an inert solvent in the presence of (NH4)2MoO4, urea, ZnCl2 and NH4Cl. The results showed that the first method gave a better yield (46%). The structures of precursors and the end product were characterized by elemental analysis, IR, 1H NMR and 13C NMR.
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