引用本文:
杨新丽, 郭益群, 刘寿长. 非晶Ru-Co/ZrO2催化苯加氢制备环己烯[J]. 应用化学,
2003, 20(4): 379-381.
Citation: YANG Xin-Li, GUO Yi-Qun, LIU Shou-Chang. Catalytic Hydrogenation of Benzene to Cyclohexene over Amorphous Ru-Co/ZrO2[J]. Chinese Journal of Applied Chemistry, 2003, 20(4): 379-381.
Citation: YANG Xin-Li, GUO Yi-Qun, LIU Shou-Chang. Catalytic Hydrogenation of Benzene to Cyclohexene over Amorphous Ru-Co/ZrO2[J]. Chinese Journal of Applied Chemistry, 2003, 20(4): 379-381.
非晶Ru-Co/ZrO2催化苯加氢制备环己烯
摘要:
非晶合金催化剂是20世纪80年代兴起的一种新型催化剂,在国内外倍受关注。这种新型催化材料由于具有潜在的高活性和高选择性而展现出良好的应用前景[1,2]。
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关键词:
- 苯
- / 催化加氢反应
- / 环己烯
- / 非晶态Ru-Co/ZrO2
English
Catalytic Hydrogenation of Benzene to Cyclohexene over Amorphous Ru-Co/ZrO2
Abstract:
A supported amorphous Ru-Co/ZrO2 catalyst was prepared by using formaldehyde as reduetant.The amorphous character of the catalyst was estimated by XRD,TG-DTA and SEM.The amorphous Ru-Co/ZrO2 catalyst has higher selectivity than Ru/ZrO2 in the selective hydrogenation of benzene to cyclohexene when the experiments were run in simulated production conditions.Presence of Co in the catalyst favored the selectivity of Ru-Co/ZrO2 but decreased its activity.
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Key words:
- benzene
- / catalytic hydrogenation
- / cyclohexene
- / amorphous Ru-Co/ZrO2
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