低共熔溶剂在绿色有机合成中的应用

引用本文: 熊兴泉, 韩骞, 石霖, 肖上运, 毕成. 低共熔溶剂在绿色有机合成中的应用[J]. 有机化学, 2016, 36(3): 480-489. doi: 10.6023/cjoc201508004 shu

Citation: Xiong Xingquan, Han Qian, Shi Lin, Xiao Shangyun, Bi Cheng. Application of Deep-Eutectic Solvents in Green Organic Synthesis[J]. Chinese Journal of Organic Chemistry, 2016, 36(3): 480-489. doi: 10.6023/cjoc201508004 shu

低共熔溶剂在绿色有机合成中的应用

1.
华侨大学材料科学与工程学院福建省高校功能材料重点实验室厦门 361021

通讯作者: 熊兴泉

基金项目:
国家自然科学基金(No. 21004024) (No. 21004024)

福建省自然科学基金(No. 2016J01063) (No. 2016J01063)

福建省高校新世纪优秀人才支持计划(No. 2012FJ-NCET-ZR03) (No. 2012FJ-NCET-ZR03)

福建省高校杰出青年科研人才培育计划(No. 11FJPY02)以及华侨大学中青年教师科研提升资助计划(No. ZQN-YX103)资助项目. (No. 11FJPY02)以及华侨大学中青年教师科研提升资助计划(No. ZQN-YX103)

摘要: 自1991年"绿色化学"的概念被提出以来, 溶剂的绿色化一直备受关注. 在过去的二十年时间里, 离子液体得到长足发展, 但是随着研究的不断深入, 离子液体的部分弊端也慢慢浮现. 在最近几年兴起了一种新型的低熔点混合物溶剂——低共熔溶剂. 与传统离子液体相比, 低共熔溶剂制备简单、价格便宜、均具有生物可降解性, 因此被用来作为一种新型绿色溶剂. 近年来, 低共熔溶剂在绿色有机合成中的应用受到了越来越多的应用. 本文重点从低共熔溶剂在环化反应、取代反应、加成反应、多组分反应以及酶催化反应等方面的应用讨论近几年来低共熔溶剂的研究进展, 并对其发展趋势进行展望.

关键词:

English

Application of Deep-Eutectic Solvents in Green Organic Synthesis

1.
Key Laboratory for Functional Materials of Fujian Higher Education, College of Materials Science and Engineering, Huaqiao University, Xiamen 361021

Corresponding author: 熊兴泉

Received Date: 05 August 2015
Available Online: 04 December 2015
Fund Project:
国家自然科学基金(No. 21004024)

福建省自然科学基金(No. 2016J01063)

福建省高校新世纪优秀人才支持计划(No. 2012FJ-NCET-ZR03)

福建省高校杰出青年科研人才培育计划(No. 11FJPY02)以及华侨大学中青年教师科研提升资助计划(No. ZQN-YX103)资助项目.

Abstract: Since the definition of "green chemistry" was proposed in 1991, the green solvents have attracted considerable attention. In the two decades ago, ionic liquids grew up. However, as following the research, it was found that ionic liquids had some drawbacks. Nowadays, some new types of low-transition-temperature mixtures, i.e. deep-eutectic solvents (DES) are raised. Compared with the traditional ionic liquids, deep-eutectic solvents are greener, cheaper and more accessible. Furthermore, the preparation methods of deep-eutectic solvents are easy, and the components of them are biodegradable. In recent years, deep-eutectic solvents have been applied as green solvents in organic synthesis widely. In this review, the application of deep-eutectic solvents in cyclization reactions, replacement reactions, addition reactions, multicomponent reactions, enzyme catalytic reactions and other reactions in the last few years are briefly summarized, and the prospects of DESs are also discussed.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

低共熔溶剂在绿色有机合成中的应用

通讯作者: 熊兴泉

English

Application of Deep-Eutectic Solvents in Green Organic Synthesis

Corresponding author: 熊兴泉

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

低共熔溶剂在绿色有机合成中的应用

通讯作者: 熊兴泉

English

Application of Deep-Eutectic Solvents in Green Organic Synthesis

Corresponding author: 熊兴泉

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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