半夹芯16电子碳硼烷化合物Me4CpCoS2C2B10H10与二茂铁炔酮的反应性

引用本文: 叶红德, 幸泽升, 胡久荣, 彭化南, 谢嘉霖, 刘林海. 半夹芯16电子碳硼烷化合物Me₄CpCoS₂C₂B₁₀H₁₀与二茂铁炔酮的反应性[J]. 无机化学学报, 2015, 31(8): 1534-1538. doi: 10.11862/CJIC.2015.138 shu

Citation: YE Hong-De, XING Ze-Sheng, HU Jiu-Rong, PENG Hua-Nan, XIE Jia-Lin, LIU Lin-Hai. Reactivity of Half-Sandwich 16e Carborane Compound Me₄CpCoS₂C₂B₁₀H₁₀ with Ferrocenyne Ketone[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(8): 1534-1538. doi: 10.11862/CJIC.2015.138 shu

半夹芯16电子碳硼烷化合物Me₄CpCoS₂C₂B₁₀H₁₀与二茂铁炔酮的反应性

叶红德 ^{1,2,
,} ,
幸泽升 ^1, ,
胡久荣 ^1, ,
彭化南 ^1, ,
谢嘉霖 ^1, ,
刘林海 ^1,

1.
1. 上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001;
2.
2. 南京大学化学化工学院, 配位化学国家重点实验室, 南京 210093

通讯作者: 叶红德,E-mail:yehongde@163.com

基金项目:
国家自然科学基金(No.21361022、21261020) (No.21361022、21261020)

江西省教育厅2014年度普通本科高校大学生创新创业教育计划项目,南京大学配位化学国家重点实验室第25批开发课题,第54批中国博士后科学基金面上基金(No.2013M541640)资助项目。 (No.2013M541640)

摘要: 邻位碳硼烷分别与正丁基锂、硫粉和Me₄CpCo(CO)I₂反应合成得到半夹芯16电子碳硼烷化合物Me₄CpCoS₂C₂B₁₀H₁₀ (1)。1与二茂铁炔酮在二氯甲烷中反应得到产物{(Me₄CpCoS₂C₂B₁₀H₁₀)[FcC(O)CHCCHCC(O)Fc]} (2)(Fc=二茂铁基)。2是一个1:2的加成产物,2个二茂铁炔酮分子以头-尾的方式加成到分子1中的1个Co-S键上。1和2分别用红外、核磁、元素分析、质谱和单晶X-射线衍射等表征方法进行了结构表征。

关键词:

半夹芯;碳硼烷;二茂铁炔酮;表征

English

Reactivity of Half-Sandwich 16e Carborane Compound Me₄CpCoS₂C₂B₁₀H₁₀ with Ferrocenyne Ketone

1.
1. Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;
2.
2. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: 叶红德,E-mail:yehongde@163.com

Received Date: 28 January 2015
Fund Project:
国家自然科学基金(No.21361022、21261020)

江西省教育厅2014年度普通本科高校大学生创新创业教育计划项目,南京大学配位化学国家重点实验室第25批开发课题,第54批中国博士后科学基金面上基金(No.2013M541640)资助项目。

Abstract: o-Carborane reacts with n-butyllithium, sulfur powder and Me₄CpCo(CO)I₂ respectively to give the half-sandwich 16e carborane compound Me₄CpCoS₂C₂B₁₀H₁₀ (1). The reaction of 1 with ferrocenyne ketone in dichloro-methane leads to the product {(Me₄CpCoS₂C₂B₁₀H₁₀)[FcC(O)CHCCHCC(O)Fc]} (2) (Fc=ferrocenyl). 2 is a 1:2 adduct. The alkynone is twofold inserted into one Co-S bond of 2 in a head-tail mode. 1 and 2 have been characterized by IR, NMR, elemental analysis, mass spectrum and single-crystal X-ray diffraction analysis. CCDC: 1045890, 1; 1045891, 2.

Key words:

half-sandwich;carborane;ferrocenyne ketone;characterization

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半夹芯16电子碳硼烷化合物Me₄CpCoS₂C₂B₁₀H₁₀与二茂铁炔酮的反应性

通讯作者: 叶红德,E-mail:yehongde@163.com

English

Reactivity of Half-Sandwich 16e Carborane Compound Me₄CpCoS₂C₂B₁₀H₁₀ with Ferrocenyne Ketone

Corresponding author: 叶红德,E-mail:yehongde@163.com

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