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2-甲酰基呋喃苯乙酰腙及其Ni(Ⅱ)配合物的晶体结构及热化学性质

杨再文 ,  丁作成 ,  刘向荣 ,  赵顺省 ,  张润兰 ,  杨水兰

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引用本文: 杨再文, 丁作成, 刘向荣, 赵顺省, 张润兰, 杨水兰. 2-甲酰基呋喃苯乙酰腙及其Ni(Ⅱ)配合物的晶体结构及热化学性质[J]. 无机化学学报, 2015, 31(8): 1520-1528. doi: 10.11862/CJIC.2015.196 shu
Citation:  YANG Zai-Wen, DING Zuo-Cheng, LIU Xiang-Rong, ZHAO Shun-Sheng, ZHANG Run-Lan, YANG Shui-Lan. Crystal Structures and Thermochemical Properties of Phenyl-acetic Acid Furan-2-ylmethylene-hydrazide and Its Ni(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(8): 1520-1528. doi: 10.11862/CJIC.2015.196 shu

2-甲酰基呋喃苯乙酰腙及其Ni(Ⅱ)配合物的晶体结构及热化学性质

  • 1.

    西安科技大学化学与化工学院, 西安 710054

    • 通讯作者: 刘向荣,E-mail:xkchemistry@163.com
  • 基金项目:

    国家自然科学基金项目(No.21373158,21301139,21103135) (No.21373158,21301139,21103135)

    陕西省教育厅科研计划项目(No.2013JK0651)资助。 (No.2013JK0651)

摘要: 以苯乙酸甲酯、水合肼和呋喃甲醛为原料,合成了配体2-甲酰基呋喃苯乙酰腙(H2L:C13H12N2O2),再与六水氯化镍反应,制得配合物Ni(HL)2 (1),并对配体及配合物进行了元素分析和X射线单晶衍射结构表征,结果表明,配体晶体属单斜晶系,P21/c空间群,晶胞参数为:a=1.161 9(3) nm,b=1.359 8(3) nm,c=0.792 16(19) nm,β=109.307(4)°;Ni(Ⅱ)配合物晶体属三斜晶系,P1空间群,晶胞参数为:a=0.455 70(14) nm,b=1.094 7(3) nm,c=1.204 8(4) nm,β=98.302(5)°。利用热重实验研究了H2L和1的热稳定性,并计算了各自热分解过程的表观活化能(Ea),发现配合物的热稳定性要远高于配体。采用微量热法研究了H2L及1与小牛胸腺DNA(CT-DNA)的相互作用,实验结果表明,配合物的作用焓值(ΔH)要大于配体的焓值,说明配合物与CT-DNA的作用要比配体与CT-DNA的作用更强。

English

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  • 收稿日期:  2014-12-25
  • 网络出版日期:  2015-05-10
通讯作者: 陈斌, bchen63@163.com
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