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Synthesis and electrochemical properties of a chiral silyl-substituted tetrathiafulvalene derivative

Guo-Qi Liang ,  Zhong-Bao Zhang ,  Hong-Qi Li ,  Ya-Ping Wang ,  Chun-Ying Xian

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Citation:  Guo-Qi Liang, Zhong-Bao Zhang, Hong-Qi Li, Ya-Ping Wang, Chun-Ying Xian. Synthesis and electrochemical properties of a chiral silyl-substituted tetrathiafulvalene derivative[J]. Chinese Chemical Letters, 2014, 25(4): 579-582. doi: 10.1016/j.cclet.2014.01.018 shu

Synthesis and electrochemical properties of a chiral silyl-substituted tetrathiafulvalene derivative

    • 通讯作者: Hong-Qi Li,
摘要: A new chiral tetrathiafulvalene (TTF) derivative and related silyl-substituted 1,3-dithiole-2-(thi)one compounds were synthesized and characterized by 1H NMR, 13C NMR, MS and IR spectra. Single crystal structure of the silyl-substituted 1,3-dithiole-2-one revealed the high degree of conjugation of the fivemembered ring moiety in the compound. The electrochemical properties of the new TTF derivative were studied by cyclic voltammetry and the results indicated that the electron-donating ability of the chiral TTF derivative was similar to that of BEDT-TTF. The ΔE value for the new TTF derivative was smaller than those for TTF and BEDT-TTF, indicative of decreased Coulombic repulsion in the dicationic redox state. Formation of charge-transfer (CT) complex between the new donor and electron acceptor 2,3-dichloro- 5,6-dicyano-1,4-benzoquinone (DDQ) was demonstrated.

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  • 发布日期:  2014-01-17
  • 收稿日期:  2013-10-07
  • 网络出版日期:  2013-12-24
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