Appended corrole manganese complexes：Catalysis and axial-ligand effect

Citation: Nga-Chun Ng, Mian HR Mahmood, Hai-Yang Liu, Fei Yam, Lam-Lung Yeung, Chi-K. Chang. Appended corrole manganese complexes：Catalysis and axial-ligand effect[J]. Chinese Chemical Letters, 2014, 25(4): 571-574. doi: 10.1016/j.cclet.2014.01.027 shu

Appended corrole manganese complexes：Catalysis and axial-ligand effect

通讯作者: Hai-Yang Liu,
Chi-K. Chang,

基金项目:
This work was supported by National Natural Science Foundation of China (Nos. 21171057, 21371059). Research Grant Council of Hong Kong under project HKUST6182/99p (Nos. 21171057, 21371059)

Area of Excellence Scheme (No. AoE/P-10/01). (No. AoE/P-10/01)

摘要: A series of N-base appended corroles and their manganese complexes were synthesized and their binding constants with three different nitrogenous ligands, triethylamine, N-methylimidazole and pyridine, were evaluated by spectroscopy. Kinetic studies indicated that the presence of appended Ndonor ligands may cause a significant enhancement of the rate of oxygen atom transfers (OAT) from (oxo)manganese(Ⅴ) corrole to alkene, and the stronger axial ligand binding has impact on the rate of the oxidation reaction. Turnover frequency (TOF) for the catalytic oxidation of alkenes by appended manganese corroles varies with the following ligand order: acetamido < pyridyl < imidazolyl. The influence of the external axial ligands on the catalytic epoxidation was investigated by using appended acetamido manganese corrole as catalyst, with the results revealing that N-methylimidazole gave the best enhancement on the yields of total oxidation products among the investigated nitrogenous ligands.

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English

Appended corrole manganese complexes：Catalysis and axial-ligand effect

1.
a Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, Hong Kong University of Science and Technology, Hong Kong, China;
2.
b Department of Chemistry, South China University of Technology, Guangzhou 510641, China;
c Department of Chemistry, Michigan State University, E.
c Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA

Corresponding author: Hai-Yang Liu, Chi-K. Chang,

Received Date: 10 October 2013
Available Online: 24 January 2014
Fund Project:

Abstract: A series of N-base appended corroles and their manganese complexes were synthesized and their binding constants with three different nitrogenous ligands, triethylamine, N-methylimidazole and pyridine, were evaluated by spectroscopy. Kinetic studies indicated that the presence of appended Ndonor ligands may cause a significant enhancement of the rate of oxygen atom transfers (OAT) from (oxo)manganese(Ⅴ) corrole to alkene, and the stronger axial ligand binding has impact on the rate of the oxidation reaction. Turnover frequency (TOF) for the catalytic oxidation of alkenes by appended manganese corroles varies with the following ligand order: acetamido < pyridyl < imidazolyl. The influence of the external axial ligands on the catalytic epoxidation was investigated by using appended acetamido manganese corrole as catalyst, with the results revealing that N-methylimidazole gave the best enhancement on the yields of total oxidation products among the investigated nitrogenous ligands.

Key words:

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Appended corrole manganese complexes：Catalysis and axial-ligand effect

通讯作者: Hai-Yang Liu,
Chi-K. Chang,

English

Appended corrole manganese complexes：Catalysis and axial-ligand effect

Corresponding author: Hai-Yang Liu, Chi-K. Chang,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Appended corrole manganese complexes：Catalysis and axial-ligand effect

通讯作者: Hai-Yang Liu, Chi-K. Chang,

English

Appended corrole manganese complexes：Catalysis and axial-ligand effect

Corresponding author: Hai-Yang Liu, Chi-K. Chang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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