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One-step co-electrodeposition of graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) film and its electrochemical studies of indole-3-acetic acid

Zi-Lan Feng ,  Yuan-Yuan Yao ,  Jing-Kun Xu ,  Long Zhang ,  Zi-Fei Wang ,  Yang-Ping Wen

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Citation:  Zi-Lan Feng, Yuan-Yuan Yao, Jing-Kun Xu, Long Zhang, Zi-Fei Wang, Yang-Ping Wen. One-step co-electrodeposition of graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) film and its electrochemical studies of indole-3-acetic acid[J]. Chinese Chemical Letters, 2014, 25(4): 511-516. doi: 10.1016/j.cclet.2014.01.004 shu

One-step co-electrodeposition of graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) film and its electrochemical studies of indole-3-acetic acid

    • 通讯作者: Jing-Kun Xu,
    Yang-Ping Wen,
  • 基金项目:

    This work was supported by the National Natural Science Foundation of China (Nos. 51263010, 51272096) (Nos. 51263010, 51272096)

    Jiangxi Provincial Department of Education (No. GJJ11590) (No. GJJ11590)

    Natural Science Foundation of Jiangxi Province (No. 2010GZH0041). (No. 2010GZH0041)

摘要: A novel graphene oxide (GO) doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) (PEDOTM) film has been achieved via one-step co-electrodeposition and utilized for electrochemical studies of indole-3-acetic acid (IAA). The incorporation of GO into PEDOTM film facilitated the electrocatalytic activity and exhibited a favorable interaction between the PEDOTM/GO film and the phytohormone during the oxidation of IAA. Under optimized conditions, differential pulse voltammetry and square wave voltammetry were used for the quantitative analysis of IAA, respectively, each exhibiting a wide linearity range from 0.6 μmol L-1 to 10 μmol L-1 and 0.05 μmol L-1 to 40 μmol L-1, good sensitivity with a low detection limit of 0.087 μmol L-1 and 0.033 μmol L-1, respectively, as well as good stability. With the notable advantages of a green, sensitive method, expeditious response and facile operation, the as-prepared PEDOTM/GO organic-inorganic composite film provides a promising platform for electrochemical studies of IAA.

English

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  • 发布日期:  2014-01-09
  • 收稿日期:  2013-10-24
  • 网络出版日期:  2013-12-17
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