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[Co(NH3)6]2[Cd8(C2O4)11(H2O)4]·8H2O：A 5-connected sqp topological metal-organic framework co-templated by Co(NH3)63+ cation and (H2O)4 cluster

Qin-He Pan ,  Rui-Jing Tian ,  Sui-Jun Liu ,  Qi-Hui Wu ,  Yuan-Yuan Zhu ,  Qiang Chen ,  Xiao-Yan Ren ,  Tong-Liang Hu

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Citation:  Qin-He Pan, Rui-Jing Tian, Sui-Jun Liu, Qi-Hui Wu, Yuan-Yuan Zhu, Qiang Chen, Xiao-Yan Ren, Tong-Liang Hu. [Co(NH3)6]2[Cd8(C2O4)11(H2O)4]·8H2O：A 5-connected sqp topological metal-organic framework co-templated by Co(NH3)63+ cation and (H2O)4 cluster[J]. Chinese Chemical Letters, 2013, 24(10): 861-865. shu

[Co(NH3)6]2[Cd8(C2O4)11(H2O)4]·8H2O：A 5-connected sqp topological metal-organic framework co-templated by Co(NH3)63+ cation and (H2O)4 cluster

    • 通讯作者: Qin-He Pan,
    Tong-Liang Hu,
  • 基金项目:

    This work was supported by the National Natural Science Foundation of China (No. 21101047) (No. 21101047)

    the Program for New Century Excellent Talents in University (No. NCET-11-0929) (No. NCET-11-0929)

    the Natural Science Foundation of Hainan Province (No. 211010) (No. 211010)

    the Priming Scientific Research Foundation of Hainan University (No. kyqd1051). (No. kyqd1051)

摘要: In our efforts to construct new metal-organic frameworks (MOFs) by template-directing method, a new cadmium oxalate, [Co(NH3)6]2[Cd8(C2O4)11(H2O)4]·8H2O (denoted HNU-1), has been synthesized under hydrothermal condition in the presence of Co(NH3)6Cl3. The crystal structure of HNU-1 was determined by single-crystal X-ray diffraction (monoclinic, C2/c), a = 11.126(2)Å, b = 17.361(4)Å, c = 16.119(3)Å, β = 102.40(3)°, V = 3040.8(10)Å3 and Z = 8. The open framework of HNU-1 contains 12-ring channels and exhibits a 5-connected sqp topological network with dinuclear Cd(Ⅱ) clusters acting as nodes. The Co(NH3)63+ cations and unusual hydrogen-bonded (H2O)4 clusters are found in the 12-ring channels with an alternative arrangement. It is believed that the (H2O)4 clusters play a co-templating role in the crystallization of HNU-1.

English

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  • 收稿日期:  2013-04-09
  • 网络出版日期:  2013-06-04
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