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金属铂(Ⅱ)-卟啉二聚体配合物的分子内π-π相互作用

苏祎伟 ,  骆开均 ,  张晨阳 ,  郭清 ,  刘汉林 ,  王燕

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引用本文: 苏祎伟, 骆开均, 张晨阳, 郭清, 刘汉林, 王燕. 金属铂(Ⅱ)-卟啉二聚体配合物的分子内π-π相互作用[J]. 无机化学学报, 2013, 29(12): 2695-2703. doi: 10.3969/j.issn.1001-4861.2013.00.386 shu
Citation:  SU Yi-Wei, LUO Kai-Jun, ZHANG Chen-Yang, GUO Qing, LIU Han-Lin, WANG Yan. Intramolecular π-π Interactions in Platinum(Ⅱ) Metalloporphyrin Dimer Homologues with Aliphatic Chains of Different Lengths[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2695-2703. doi: 10.3969/j.issn.1001-4861.2013.00.386 shu

金属铂(Ⅱ)-卟啉二聚体配合物的分子内π-π相互作用

  • 基金项目:

    国家自然科学基金(No.21072141，21172161)资助项目。 (No.21072141，21172161)

摘要: 合成了以不同链长的烷氧基柔性链相连接的金属铂(Ⅱ)-卟啉二聚体配合物并对其热稳定性，光谱性质及电化学性质做了研究。在浓度由10-7 mol·dm-3增大到10-3 mol·dm-3的过程中将配体与配合物的紫外-可见吸收光谱与光致发光光谱做了对比，发现配体与配合物的吸收光谱随浓度变化未出现改变，但发射光谱显现出随浓度增大而产生红移现象。当烷氧基柔性链中碳原子数大于4时，C6与C10配合物无论是高浓度下的溶液与升华固体薄膜中的荧光发射光谱均比配体有明显的红移，而短链的配合物无此性质。

English

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  • 收稿日期:  2013-04-11
  • 网络出版日期:  2013-07-18
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