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四溴代对苯二甲酸根及二吡啶基丙烷构筑的锌(Ⅱ)及镉(Ⅱ)配位聚合物的合成及晶体结构

吕旭燕 ,  刘建锋 ,  刘艳 ,  高玲玲 ,  肖立群 ,  胡拖平

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引用本文: 吕旭燕, 刘建锋, 刘艳, 高玲玲, 肖立群, 胡拖平. 四溴代对苯二甲酸根及二吡啶基丙烷构筑的锌(Ⅱ)及镉(Ⅱ)配位聚合物的合成及晶体结构[J]. 无机化学学报, 2013, 29(5): 1096-1102. doi: 10.3969/j.issn.1001-4861.2013.00.175 shu
Citation:  LV Xu-Yan, LIU Jian-Feng, LIU Yan, GAO Ling-Ling, XIAO Li-Qun, HU Tuo-Ping. Syntheses and Crystal Structures of Zn(Ⅱ) and Cd(Ⅱ) Complexes Based on 2,3,5,6-Tetrabromoterephthalic Acid and 1,3-Bis(4-pyridyl)propane[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(5): 1096-1102. doi: 10.3969/j.issn.1001-4861.2013.00.175 shu

四溴代对苯二甲酸根及二吡啶基丙烷构筑的锌(Ⅱ)及镉(Ⅱ)配位聚合物的合成及晶体结构

    通讯作者: 胡拖平,E-mail:hutuopingsx@yahoo.com.cn
  • 基金项目:

    国家国际科技合作(No.2011DFA51980) (No.2011DFA51980)

    省自然科学基金(No.2011081022)资助项目。 (No.2011081022)

摘要: 在室温和甲醇/水溶液为溶剂的条件下,以四溴代对苯二甲酸(H2TBTA)及1,3-二(4-吡啶基)丙烷(BPP)为配体合成了[Zn(TBTA)(BPP)]n (1)和[Cd(TBTA)(BPP)2(H2O)2]n (2)2个配位聚合物,对其进行了X-射线单晶衍射、元素分析、红外光谱分析和热重等性质表征。结果表明:配合物1为二维(2D)层状网络结构;配合物2为一维(1D)链状结构;H2TBTA配体中的羧基都采取单齿模式与金属离子配位;配合物中的氢键作用对其结构的稳定性起关键作用。

English

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  • 收稿日期:  2012-07-26
  • 网络出版日期:  2013-01-23
通讯作者: 陈斌, bchen63@163.com
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