注册 English

双功能[Sn,Al]-Beta分子筛一步催化葡萄糖生成5-羟甲基糠醛

李良 ,  丁姜宏 ,  蒋金刚 ,  朱治国 ,  吴鹏

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引用本文: 李良, 丁姜宏, 蒋金刚, 朱治国, 吴鹏. 双功能[Sn,Al]-Beta分子筛一步催化葡萄糖生成5-羟甲基糠醛[J]. 催化学报, 2015, 36(6): 820-828. doi: 10.1016/S1872-2067(14)60287-4 shu
Citation:  Liang Li, Jianghong Ding, Jin-Gang Jiang, Zhiguo Zhu, Peng Wu. One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts[J]. Chinese Journal of Catalysis, 2015, 36(6): 820-828. doi: 10.1016/S1872-2067(14)60287-4 shu

双功能[Sn,Al]-Beta分子筛一步催化葡萄糖生成5-羟甲基糠醛

    通讯作者: 吴鹏,电话/传真: (021)62232292; 电子信箱: pwu@chem.ecnu.edu.cn
  • 基金项目:

    国家自然科学基金(21373089, U1162102) (21373089, U1162102)

    教育部博士学科点专项科研基金(2012007613000) (2012007613000)

    国家科技支撑计划(2012BAE05B02) (2012BAE05B02)

    上海市重点学科建设项目资助(B409). (B409)

摘要: 以部分脱铝的Beta分子筛为母体, 采用同晶置换法将Sn植入骨架制备双功能[Sn,Al]-Beta分子筛, 并应用于葡萄糖一步催化生成5-羟甲基糠醛(5-HMF)反应中. 样品中Sn与Al的含量通过酸洗的浓度和酸洗的时间以及SnCl4处理的时间来控制. 由于骨架中有与Al相关为B酸位, 和Sn相关的L酸位, [Sn,Al]-Beta可作为一种双功能的固体酸催化剂. 优化了[Sn,Al]-Beta催化葡萄糖一步催化生成5-HMF的反应参数, 在最优Sn/Al比条件下, 葡萄糖转化率为60.0%, 5-HMF选择性为62.1%.

English

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  • 发布日期:  2015-06-20
  • 收稿日期:  2014-11-28
  • 网络出版日期:  2015-01-13
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