Immobilization of chiral Rh catalyst on glass and application to asymmetric transfer hydrogenation of aryl ketones in aqueous media

Tan-Yu Cheng Jing-Lan Zhuang Hui Yao Huai-Sheng Zhang Guo-Hua Liu

Citation:  Tan-Yu Cheng, Jing-Lan Zhuang, Hui Yao, Huai-Sheng Zhang, Guo-Hua Liu. Immobilization of chiral Rh catalyst on glass and application to asymmetric transfer hydrogenation of aryl ketones in aqueous media[J]. Chinese Chemical Letters, 2014, 25(4): 613-616. doi: 10.1016/j.cclet.2014.01.007 shu

Immobilization of chiral Rh catalyst on glass and application to asymmetric transfer hydrogenation of aryl ketones in aqueous media

    通讯作者: Tan-Yu Cheng,
    Guo-Hua Liu,
摘要: A chiral catalyst, Cp*RhTsDPEN (Cp* = pentamethyl cyclopentadiene, TsDPEN = substitutive phenylsulfonyl-1,2-diphenylethylenediamine), was synthesized and immobilized at the surface of glass. The immobilized catalyst exhibited good catalytic efficiency for asymmetric transfer hydrogenation of aromatic ketones in water with HCOONa as hydrogen source.

English

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  • 发布日期:  2014-01-10
  • 收稿日期:  2013-10-07
  • 网络出版日期:  2013-12-24
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