注册 English

含二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸的Co(Ⅱ)配合物的合成、晶体结构及光催化性能研究

施伟东 ,  任傲 ,  刘春波 ,  白红叶 ,  车广波 ,  孙赫一 ,  丛尧

downloadPDF
引用本文: 施伟东, 任傲, 刘春波, 白红叶, 车广波, 孙赫一, 丛尧. 含二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸的Co(Ⅱ)配合物的合成、晶体结构及光催化性能研究[J]. 无机化学学报, 2013, 29(12): 2649-2654. doi: 10.3969/j.issn.1001-4861.2013.00.404 shu
Citation:  SHI Wei-Dong, REN Ao, LIU Chun-Bo, BAI Hong-Ye, CHE Guang-Bo, SUN He-Yi, CONG Yao. Synthesis, Crystal Structure and Photocatalytic Property of Co(Ⅱ) Compound with Dipyrido[3,2-a∶2’,3’-c]-phenazine-2-carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2649-2654. doi: 10.3969/j.issn.1001-4861.2013.00.404 shu

含二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸的Co(Ⅱ)配合物的合成、晶体结构及光催化性能研究

  • 基金项目:

    国家科学自然基金(No.61205040)，江苏大学自然科学基金(No.09JDG001，11jdg104)，江苏省自然科学基金(No.BK2012701，BK2011528)资助项目。 (No.61205040)，江苏大学自然科学基金(No.09JDG001，11jdg104)，江苏省自然科学基金(No.BK2012701，BK2011528)

摘要: 本文利用二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸(HDPPZC)作为有机配体在水热条件下制备了配合物[CoCl0.5(H2O)0.5(HDPPZC)2](PW12O40)0.5·3.5H2O (1)，利用X-射线单晶衍射、元素分析、紫外可见吸收光谱和差热分析对该化合物的结构进行了表征。单晶结构分析表明该晶体属于三斜晶系，P1空间群，晶胞系数a=1.036 0(2) nm，b=1.564 0(3) nm，c=1.656 0(3) nm，α=80.99(3)°，β=84.93(3)°，γ=85.44(3)°，V=2.6339(9) nm3，Z=1。配合物1是由零维离散结构通过氢键和π-π堆积形成的二维超分子结构。本文还研究了该化合物对罗丹明B的光催化降解性质。

English

  • 

    1. [1] Murray L J, Dinca M, Long J R. Chem. Soc. Rev., 2009, 38: 1294-1314[1] Murray L J, Dinca M, Long J R. Chem. Soc. Rev., 2009, 38: 1294-1314

    2. [2] James S L. Chem. Soc. Rev., 2003, 32:276-288[2] James S L. Chem. Soc. Rev., 2003, 32:276-288

    3. [3] Ferey G. Nat. Mater., 2003, 2:136-137[3] Ferey G. Nat. Mater., 2003, 2:136-137

    4. [4] Zeng M H, Wang Q X, Tan Y X, et al. J. Am. Chem. Soc., 2010, 132:2561-2563[4] Zeng M H, Wang Q X, Tan Y X, et al. J. Am. Chem. Soc., 2010, 132:2561-2563

    5. [5] Silva C G, Corma A, Garcia H. J. Mater. Chem., 2010, 20: 3141-3156[5] Silva C G, Corma A, Garcia H. J. Mater. Chem., 2010, 20: 3141-3156

    6. [6] Liu W T, Ou Y C, Xie Y L, et al. Eur. J. Inorg. Chem., 2009, 28:4213-4218[6] Liu W T, Ou Y C, Xie Y L, et al. Eur. J. Inorg. Chem., 2009, 28:4213-4218

    7. [7] ZHAO Nan (赵楠), DENG Hong-Ping (邓洪平), SHU Mou-Hai (舒谋海), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (7):1213-1217[7] ZHAO Nan (赵楠), DENG Hong-Ping (邓洪平), SHU Mou-Hai (舒谋海), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (7):1213-1217

    8. [8] LIU Tong-Fei (刘同飞), CUI Guang-Hua (崔广华), JIAO Cui-Huan (焦翠欢), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (7):1417-1422[8] LIU Tong-Fei (刘同飞), CUI Guang-Hua (崔广华), JIAO Cui-Huan (焦翠欢), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (7):1417-1422

    9. [9] Liao Z L, Li G D, Bi M H, et al. Inorg. Chem., 2008, 47: 4844-4853[9] Liao Z L, Li G D, Bi M H, et al. Inorg. Chem., 2008, 47: 4844-4853

    10. [10] Lin H S, Maggard P A. Inorg. Chem., 2008, 47:8044-8052[10] Lin H S, Maggard P A. Inorg. Chem., 2008, 47:8044-8052

    11. [11] Yu Z T, Liao Z L, Jiang Y S, et al. Chem.-A Eur. J., 2005, 11:2642-2650[11] Yu Z T, Liao Z L, Jiang Y S, et al. Chem.-A Eur. J., 2005, 11:2642-2650

    12. [12] Alvaro M, Carbonell E, Ferrer B, et al. Chem. Eur. J., 2007, 13:5106-5112[12] Alvaro M, Carbonell E, Ferrer B, et al. Chem. Eur. J., 2007, 13:5106-5112

    13. [13] Du J J, Yuan Y P, Sun J X, et al. J. Hazard. Mater., 2011, 190:945-951[13] Du J J, Yuan Y P, Sun J X, et al. J. Hazard. Mater., 2011, 190:945-951

    14. [14] Wen L L, Wang F, Feng J, et al. Cryst. Growth Des., 2009, 9:3581-3589[14] Wen L L, Wang F, Feng J, et al. Cryst. Growth Des., 2009, 9:3581-3589

    15. [15] Che G B, Chen J, Wang X C, et al. Inorg. Chem. Commun., 2011, 14:1086-1088[15] Che G B, Chen J, Wang X C, et al. Inorg. Chem. Commun., 2011, 14:1086-1088

    16. [16] Gholamkhass B, Koike K, Negishi N, et al. Inorg. Chem., 2001, 40:756-765[16] Gholamkhass B, Koike K, Negishi N, et al. Inorg. Chem., 2001, 40:756-765

    17. [17] Sheldrick G M. SHELXS-97, Programs for X-ray Crystal Structure Solution, University of Göttingen: Göttingen, Germany, 1997.[17] Sheldrick G M. SHELXS-97, Programs for X-ray Crystal Structure Solution, University of Göttingen: Göttingen, Germany, 1997.

    18. [18] Sheldrick G M. SHELXL-97, Programs for X-ray Crystal Structure Refinement, University of Göttingen: Göttingen, Germany, 1997.[18] Sheldrick G M. SHELXL-97, Programs for X-ray Crystal Structure Refinement, University of Göttingen: Göttingen, Germany, 1997.

    19. [19] Farrugia L J. WINGX, A Windows Program for Crystal Structure Analysis, University of Glasgow: Glasgow, United Kingdom, 1988.[19] Farrugia L J. WINGX, A Windows Program for Crystal Structure Analysis, University of Glasgow: Glasgow, United Kingdom, 1988.

    20. [20] Zhang G, Choi W. Chem. Commun., 2012, 48:10621-10623[20] Zhang G, Choi W. Chem. Commun., 2012, 48:10621-10623

    21. [21] Aarthi T, Madras G. Ind. Eng. Chem. Res., 2007, 46 (1):7-14[21] Aarthi T, Madras G. Ind. Eng. Chem. Res., 2007, 46 (1):7-14

    22. [22] Anna K, Marcos F G, Gerardo C. Chem. Rev., 2012, 112 (3): 1555-1614[22] Anna K, Marcos F G, Gerardo C. Chem. Rev., 2012, 112 (3): 1555-1614

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  741
  • HTML全文浏览量:  107
文章相关
  • 收稿日期:  2013-05-14
  • 网络出版日期:  2013-10-09
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net