以PW9为结构基元构筑的夹心型多金属氧酸盐化合物的合成与晶体结构

冯秀玲

引用本文: 冯秀玲. 以PW9为结构基元构筑的夹心型多金属氧酸盐化合物的合成与晶体结构[J]. 无机化学学报, 2013, 29(12): 2603-2608. doi: 10.3969/j.issn.1001-4861.2013.00.366 shu
Citation:  FENG Xiu-Ling. Synthesis and Crystal Structure of a Sandwich-Type Polyoxometalate Built up of the PW9 Unit[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2603-2608. doi: 10.3969/j.issn.1001-4861.2013.00.366 shu

以PW9为结构基元构筑的夹心型多金属氧酸盐化合物的合成与晶体结构

  • 基金项目:

    湖南省教育厅(No.12C0839)资助项目。 (No.12C0839)

摘要: 通过水热合成方法合成了以夹心多酸阴离子{Ni4(H2O)2(PW9O34)2}10-,乙二胺(en)和Ni(Ⅱ)构筑的夹心型多金属氧酸盐化合物[Ni(en)2]2[{Ni(en)2}{Ni(en)2H2O}2{(PW9O34)2Ni4(H2O)2}]·16H2O(1),采用IR、单晶X-射线衍射法、TG/DTG及循环伏安法对标题化合物进行结构和性质研究。该化合物的夹心多酸阴离子通过[Ni(en)2]2+连接形成一维链,并进一步通过氢键作用形成3D超分子结构。

English

  • 
    1. [1] Niu J Y, Wang K H, Chen H N, et al. Cryst. Growth Des., 2009, 9:4362-4372[1] Niu J Y, Wang K H, Chen H N, et al. Cryst. Growth Des., 2009, 9:4362-4372

    2. [2] Mialane P, Dolbecq A, Marrot J, et al. Chem. Eur. J., 2005, 11:1771-1778[2] Mialane P, Dolbecq A, Marrot J, et al. Chem. Eur. J., 2005, 11:1771-1778

    3. [3] Kortz U, Hussian F, Reicke M. Angew. Chem. Int. Ed., 2005, 44:3773-3777[3] Kortz U, Hussian F, Reicke M. Angew. Chem. Int. Ed., 2005, 44:3773-3777

    4. [4] Mialane P, Dolbecq A, Sé cheresse F. Chem. Commun., 2006, 33:3477-3485[4] Mialane P, Dolbecq A, Sé cheresse F. Chem. Commun., 2006, 33:3477-3485

    5. [5] Sankarraj A V. Thesis for the Doctorate of Auburn University. 2008.[5] Sankarraj A V. Thesis for the Doctorate of Auburn University. 2008.

    6. [6] Han Q X, Liu Y, Li J, et al. Chiese J. Struct. Chem., 2009, 28:25-28[6] Han Q X, Liu Y, Li J, et al. Chiese J. Struct. Chem., 2009, 28:25-28

    7. [7] LI Xin-Xiong (李新雄), FANG Wei-Hui (芳伟慧), YANG Guo-Yu (杨国昱). Chem. J. Chinese Universities (Gaodeng Xuexiao Huaxue Xuebao), 2011, 32:571-576[7] LI Xin-Xiong (李新雄), FANG Wei-Hui (芳伟慧), YANG Guo-Yu (杨国昱). Chem. J. Chinese Universities (Gaodeng Xuexiao Huaxue Xuebao), 2011, 32:571-576

    8. [8] Wu J, Wang C X, Su Z H, et al. Chinese J. Struct. Chem., 2012, 31:271-279[8] Wu J, Wang C X, Su Z H, et al. Chinese J. Struct. Chem., 2012, 31:271-279

    9. [9] Li B, Zhao D, Zheng S T, et al. J. Clust. Sci., 2008, 19:641-650[9] Li B, Zhao D, Zheng S T, et al. J. Clust. Sci., 2008, 19:641-650

    10. [10] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.[10] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.

    11. [11] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.[11] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.

    12. [12] Weakley T J R, Evans Jr H T, Showell J S, et al. J. Chem. Soc. Chem. Commun., 1973, 4:139-140[12] Weakley T J R, Evans Jr H T, Showell J S, et al. J. Chem. Soc. Chem. Commun., 1973, 4:139-140

    13. [13] Claud R D, Michael F, Raymonde F, et al. Inorg. Chem., 1983, 22:207-216[13] Claud R D, Michael F, Raymonde F, et al. Inorg. Chem., 1983, 22:207-216

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  • 收稿日期:  2013-02-26
  • 网络出版日期:  2013-06-13
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