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三联吡啶羧基Zn(Ⅱ)，Cu(Ⅱ)和Fe(Ⅱ)配合物研究

胡斌 ,  颜流水 ,  吴美凤 ,  邓春健 ,  黄伟

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引用本文: 胡斌, 颜流水, 吴美凤, 邓春健, 黄伟. 三联吡啶羧基Zn(Ⅱ)，Cu(Ⅱ)和Fe(Ⅱ)配合物研究[J]. 无机化学学报, 2013, 29(12): 2595-2602. doi: 10.3969/j.issn.1001-4861.2013.00.393 shu
Citation:  HU Bin, YAN Liu-Shui, WU Mei-Feng, DENG Chun-Jian, HUANG Wei. Studies of Zinc(Ⅱ), Copper(Ⅱ) and Ferrous(Ⅱ) Complexes Having a Tridentate [2,2’∶6’,2"-Terpyridine]-4’-carboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2595-2602. doi: 10.3969/j.issn.1001-4861.2013.00.393 shu

三联吡啶羧基Zn(Ⅱ)，Cu(Ⅱ)和Fe(Ⅱ)配合物研究

  • 基金项目:

    国家自然科学基金(No.21165013，21171088)；中国博士后基金(No.2012M511720)；江西省自然科学基金(No.2010GZH0112)；江西省教育厅科技(青年)基金(No.DB201302155)南昌航空大学博士基金(No.EA201102327)资助项目。 (No.21165013，21171088)；中国博士后基金(No.2012M511720)；江西省自然科学基金(No.2010GZH0112)；江西省教育厅科技(青年)基金(No.DB201302155)南昌航空大学博士基金(No.EA201102327)

摘要: 本文通过溶剂热法合成了三个基于4’-羧基-2，2’∶6’，2"-三联吡啶(HL)的单核配合物，其分子式为[ML2]·4H2O(1，M=Zn(Ⅱ)；2，M=Cu(Ⅱ)；3，M=Fe(Ⅱ))，并分别对其进行了元素分析、波谱、单晶和粉末衍射表征。晶体结构测试结果表明3个配合物为异质同晶结构，都属于四方晶系的I42d空间群。配合物1~3都是1个二价金属离子和2个羧基未配位且去质子化的三齿螯合配体L配位形成的单核结构，通过分子间π-π堆积和氢键作用拓展成三维超分子网络结构。由于二价Zn离子的全充满d10电子构型，配合物1与其配体相比具有明显的室温固态蓝色荧光发射性质。

English

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  • 收稿日期:  2013-02-22
  • 网络出版日期:  2013-08-06
通讯作者: 陈斌, bchen63@163.com
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