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Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物

孙岳 ,  张先徽 ,  那延祥 ,  李昌立 ,  冯克成

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引用本文: 孙岳, 张先徽, 那延祥, 李昌立, 冯克成. Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物[J]. 无机化学学报, 2013, 29(12): 2568-2574. doi: 10.3969/j.issn.1001-4861.2013.00.401 shu
Citation:  SUN Yue, ZHANG Xian-Hui, NA Yan-Xiang, LI Chang-Li, FENG Ke-Cheng. Construction of Organic-Inorganic Hybrid from Dawson-Type Tungstophosphate and Tetranuclear Copper Complex[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2568-2574. doi: 10.3969/j.issn.1001-4861.2013.00.401 shu

Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物

摘要: 通过水热合成得到了一个新颖的包含四核铜配合物的无机-有机杂化化合物[CuCl(H2O)4)][CuCl(H2O)(Phen)][{(CuPhen)2Cl2}2(bdc)]2[P2W18O62]·5H2O (1)(Phen=1，10-phenanthroline和bdc=1，4-benzenedicarboxylate)，对其进行了元素分析、红外光谱、热重、电化学等表征，并用X-射线单晶衍射测定了它的晶体结构。化合物1含有由Cl和bdc桥连的四核铜配合物阳离子[{(CuPhen)2Cl2}2(bdc)]2+。此外，化合物1的电化学研究表明其对亚硝酸的还原具有很好的电催化活性。

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  • 收稿日期:  2012-07-16
  • 网络出版日期:  2013-06-06
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