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硫酸铜掺杂TiO2涂层对碳纤维抗氧化性能的影响

王勇 ,  余海鹏 ,  胡永琪 ,  赵瑞红 ,  李飞龙 ,  张文娇 ,  张兆翔

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引用本文: 王勇, 余海鹏, 胡永琪, 赵瑞红, 李飞龙, 张文娇, 张兆翔. 硫酸铜掺杂TiO2涂层对碳纤维抗氧化性能的影响[J]. 无机化学学报, 2013, 29(12): 2549-2554. doi: 10.3969/j.issn.1001-4861.2013.00.403 shu
Citation:  WANG Yong, YU Hai-Peng, HU Yong-Qi, ZHAO Rui-Hong, LI Fei-Long, ZHANG Wen-Jiao, ZHANG Zhao-Xiang. Influence of CuSO4 Doping on the Oxidation Resistance of TiO2-Coated Carbon Fibers[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2549-2554. doi: 10.3969/j.issn.1001-4861.2013.00.403 shu

硫酸铜掺杂TiO2涂层对碳纤维抗氧化性能的影响

  • 基金项目:

    河北省自然科学基金(B2013208155) (B2013208155)

    国家自然科学基金(No.60578041)资助项目。 (No.60578041)

摘要: 采用溶胶-浸渍法，以CuSO4为烧结助剂在碳纤维表面制得TiO2涂层。利用XRD、SEM和TEM分析了涂层相组成及形貌，通过静态等温氧化实验考察了涂层碳纤维抗氧化性能。结果表明：掺杂CuSO4制备TiO2涂层均匀完整致密，涂层相组成均为锐钛矿型TiO2，且涂层厚度从45 nm提高至185 nm；与普通TiO2涂层碳纤维相比，完全氧化温度从667 ℃上升到800 ℃，氧化活化能从118.390 kJ·mol-1提高到152.562 kJ·mol-1，CuSO4的掺杂大大提高了TiO2涂层碳纤维的抗氧化性能。

English

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  • 收稿日期:  2013-05-27
  • 网络出版日期:  2013-07-31
通讯作者: 陈斌, bchen63@163.com
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