五乙烯六胺修饰的MCF基吸附剂的制备及其CO<sub>2</sub>吸附性能研究

引用本文: 冯星星, 谢菁, 胡庚申, 贾爱平, 谢冠群, 罗孟飞. 五乙烯六胺修饰的MCF基吸附剂的制备及其CO₂吸附性能研究[J]. 物理化学学报, 2013, 29(06): 1266-1272. doi: 10.3866/PKU.WHXB201304091 shu

Citation: FENG Xing-Xing, XIE Jing, HU Geng-Shen, JIA Ai-Ping, XIE Guan-Qun, LUO Meng-Fei. Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO₂ Adsorption[J]. Acta Physico-Chimica Sinica, 2013, 29(06): 1266-1272. doi: 10.3866/PKU.WHXB201304091 shu

五乙烯六胺修饰的MCF基吸附剂的制备及其CO₂吸附性能研究

基金项目:
国家自然科学基金(21203167)资助项目 (21203167)

摘要:

以三嵌段共聚物P123 (EO₂₀-PO₇₀-EO₂₀)为模板剂合成了介孔泡沫氧化硅(MCF)材料. MCF经过五乙烯六胺(PEHA)修饰后用于捕捉CO₂. 采用扫描电镜(SEM)、透射电镜(TEM)、N2吸附-脱附、傅里叶变换红外(FTIR)光谱、热重分析(TGA)对MCF和MCF-PEHA进行了表征. 结果表明, PEHA对MCF改性后, 并没有破坏MCF载体本身的结构. MCF-PEHA的CO₂吸附量在75℃时达到最大. 随着PEHA含量的增加, MCF-PEHA的CO₂吸附量呈先增大后减小的趋势, 当PEHA含量为70% (w)时, CO₂吸附量达到最大, 为3.55 mmol·g^-1. 水汽促进了吸附剂的CO₂吸附性能. 研究结果还表明, MCF-70吸附剂经过四次吸脱附循环, 吸附性能基本保持不变, 表现出很好的可再生性能.

关键词:

English

Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO₂ Adsorption

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
Received Date: 27 December 2012
Available Online: 17 May 2013
Fund Project:
国家自然科学基金(21203167)资助项目

Abstract:

Mesocellular silica foam (MCF) was prepared using P123 (EO₂₀-PO₇₀-EO₂₀) as template and then functionalized with pentaethylenehexamine (PEHA) for CO₂ adsorption. The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorptiondesorption isotherms, Fourier transform infrared (FTIR) spectroscopy and thermal gravimetric analysis (TGA). These results indicated that after modification with PEHA, the structure of the support itself was undamaged. The highest CO₂ adsorption capacity of MCF-PEHA was obtained at 75℃. With increasing PEHA loading, the CO₂ adsorption capacity increases and approached the highest adsorption capacity (3.55 mmol·g^-1) with a 70% (w) PEHA loading. Moisture improved the CO₂ adsorption performance of the adsorbents. Repeated adsorption-desorption cycling indicated that the sorbents maintained stable CO₂ adsorption capacity after 4 cycles, indicating potential for regeneration of the adsorbents.

Key words:

1. [1]
  
  (1) Lee, S. S.; Mun, S. M.; Choi,W. J.; Min, B. M.; Cho, S.W.; Oh,K. J. J. Environ. Sci. 2012, 24, 897. doi: 10.1016/S1001-0742(11)60788-2
  (1) Lee, S. S.; Mun, S. M.; Choi,W. J.; Min, B. M.; Cho, S.W.; Oh,K. J. J. Environ. Sci. 2012, 24, 897. doi: 10.1016/S1001-0742(11)60788-2
2. [2]
  (2) Zhang, J.; Misch, R.; Tan, Y.; Agar, D.W. Chem. Eng. Technol.2011, 34, 1481. doi: 10.1002/ceat.v34.9(2) Zhang, J.; Misch, R.; Tan, Y.; Agar, D.W. Chem. Eng. Technol.2011, 34, 1481. doi: 10.1002/ceat.v34.9
3. [3]
  (3) Kemper, J.; Ewert, G.; Grünewald, M. Energy Procedia 2011, 4,232. doi: 10.1016/j.egypro.2011.01.046(3) Kemper, J.; Ewert, G.; Grünewald, M. Energy Procedia 2011, 4,232. doi: 10.1016/j.egypro.2011.01.046
4. [4]
  (4) Du, M.; Feng, B.; An, H.; Liu,W.; Zhang, L. Korean J. Chem. Eng. 2012, 29, 362. doi: 10.1007/s11814-011-0184-4(4) Du, M.; Feng, B.; An, H.; Liu,W.; Zhang, L. Korean J. Chem. Eng. 2012, 29, 362. doi: 10.1007/s11814-011-0184-4
5. [5]
  (5) Chew, T. L.; Ahmad, L. A.; Bhatia, S. Adv. Colloid Interface Sci.2010, 153, 43. doi: 10.1016/j.cis.2009.12.001(5) Chew, T. L.; Ahmad, L. A.; Bhatia, S. Adv. Colloid Interface Sci.2010, 153, 43. doi: 10.1016/j.cis.2009.12.001
6. [6]
  (6) Wang, M.; Yang, D.;Wang, Z.;Wang, J.;Wang, S. Front. Chem. Eng. Chin. 2010, 4, 127. doi: 10.1007/s11705-009-0231-4(6) Wang, M.; Yang, D.;Wang, Z.;Wang, J.;Wang, S. Front. Chem. Eng. Chin. 2010, 4, 127. doi: 10.1007/s11705-009-0231-4
7. [7]
  (7) Lee, S. C.; Choi, B. Y.; Lee, T. J.; Ryu, C. K.; Ahn, Y. S.; Kim,J. C. Catal. Today 2006, 111, 385. doi: 10.1016/j.cattod.2005.10.051(7) Lee, S. C.; Choi, B. Y.; Lee, T. J.; Ryu, C. K.; Ahn, Y. S.; Kim,J. C. Catal. Today 2006, 111, 385. doi: 10.1016/j.cattod.2005.10.051
8. [8]
  (8) Choi, S.; Drese, J. H.; Eisenberger, P. M.; Jones, C.W. Environ. Sci. Technol. 2011, 45, 2420. doi: 10.1021/es102797w(8) Choi, S.; Drese, J. H.; Eisenberger, P. M.; Jones, C.W. Environ. Sci. Technol. 2011, 45, 2420. doi: 10.1021/es102797w
9. [9]
  (9) Gray, M. L.; Hoffman, J. S.; Hreha, D. C.; Fauth, D. J.; Hedges,S.W.; Champagne, K. J.; Pennline, H.W. Energy Fuels 2009,23, 4840. doi: 10.1021/ef9001204(9) Gray, M. L.; Hoffman, J. S.; Hreha, D. C.; Fauth, D. J.; Hedges,S.W.; Champagne, K. J.; Pennline, H.W. Energy Fuels 2009,23, 4840. doi: 10.1021/ef9001204
10. [10]
  (10) Hu, G. S.; Zhu, L.; Jia, A. P.; Hu, X.; Lu, J. Q.; Luo, M. F. Appl. Spectrosc. 2012, 66, 122. doi: 10.1366/11-06466(10) Hu, G. S.; Zhu, L.; Jia, A. P.; Hu, X.; Lu, J. Q.; Luo, M. F. Appl. Spectrosc. 2012, 66, 122. doi: 10.1366/11-06466
11. [11]
  (11) Wei, L.; Lan, R. K.; Jing, Y.; Gao, Z. M.;Wang, Y. D. Chem. Ind. Eng. Prog. 2011, 30, 143. [韦力, 蓝任凯, 靖宇, 高正明, 王运冬. 化工进展, 2011, 30, 143.](11) Wei, L.; Lan, R. K.; Jing, Y.; Gao, Z. M.;Wang, Y. D. Chem. Ind. Eng. Prog. 2011, 30, 143. [韦力, 蓝任凯, 靖宇, 高正明, 王运冬. 化工进展, 2011, 30, 143.]
12. [12]
  (12) Xu, X.; Song, C.; Andresen, J. M.; Miller, B. G.; Scaroni, A.W.Energy Fuels 2002, 16, 1463. doi: 10.1021/ef020058u(12) Xu, X.; Song, C.; Andresen, J. M.; Miller, B. G.; Scaroni, A.W.Energy Fuels 2002, 16, 1463. doi: 10.1021/ef020058u
13. [13]
  (13) Ye, Q.; Zhang, Y.; Li, M.; Shi, Y. Acta Phys. -Chin.Sin. 2012, 28,1223. [叶青, 张瑜, 李茗, 施耀. 物理化学学报,2012, 28, 1223.] doi: 10.3866/PKU.WHXB201202234(13) Ye, Q.; Zhang, Y.; Li, M.; Shi, Y. Acta Phys. -Chin.Sin. 2012, 28,1223. [叶青, 张瑜, 李茗, 施耀. 物理化学学报,2012, 28, 1223.] doi: 10.3866/PKU.WHXB201202234
14. [14]
  (14) Belmabkhout, Y.; Serna-Guerrero, R.; Sayari, A. Ind. Eng. Chem. Res. 2010, 49, 359. doi: 10.1021/ie900837t(14) Belmabkhout, Y.; Serna-Guerrero, R.; Sayari, A. Ind. Eng. Chem. Res. 2010, 49, 359. doi: 10.1021/ie900837t
15. [15]
  (15) Kim, S.; Ida, J.; Guliants, V. V.; Lin, J. Y. S. J. Phys. Chem. B2005, 109, 6287. doi: 10.1021/jp045634x(15) Kim, S.; Ida, J.; Guliants, V. V.; Lin, J. Y. S. J. Phys. Chem. B2005, 109, 6287. doi: 10.1021/jp045634x
16. [16]
  (16) Wang, L.; Ma, L.;Wang, A.; Liu, Q.; Zhang, T. Chin. J. Catal.2007, 28, 805. doi: 10.1016/S1872-2067(07)60066-7(16) Wang, L.; Ma, L.;Wang, A.; Liu, Q.; Zhang, T. Chin. J. Catal.2007, 28, 805. doi: 10.1016/S1872-2067(07)60066-7
17. [17]
  (17) Zheng, F.; Tran, D. N.; Busche, B. J.; Fryxell, G. E.; Addleman,R. S.; Zemanian, T. S.; Aardahl, C. L. Ind. Eng. Chem. Res.2005, 44, 3099. doi: 10.1021/ie049488t(17) Zheng, F.; Tran, D. N.; Busche, B. J.; Fryxell, G. E.; Addleman,R. S.; Zemanian, T. S.; Aardahl, C. L. Ind. Eng. Chem. Res.2005, 44, 3099. doi: 10.1021/ie049488t
18. [18]
  (18) Zelenak, V.; Halamova, D.; Gaberova, L.; Bloch, E.; Llewellyn,P. Microporous Mesoporous Mat. 2008, 116, 358. doi: 10.1016/j.micromeso.2008.04.023(18) Zelenak, V.; Halamova, D.; Gaberova, L.; Bloch, E.; Llewellyn,P. Microporous Mesoporous Mat. 2008, 116, 358. doi: 10.1016/j.micromeso.2008.04.023
19. [19]
  (19) Knofel, C.; Descarpentries, J.; Benzaouia, A.; Zelenak, V.;Mornet, S.; Llewellyn, P. L.; Hornebecq, V. Microporous Mesoporous Mat. 2007, 99, 79. doi: 10.1016/j.micromeso.2006.09.018(19) Knofel, C.; Descarpentries, J.; Benzaouia, A.; Zelenak, V.;Mornet, S.; Llewellyn, P. L.; Hornebecq, V. Microporous Mesoporous Mat. 2007, 99, 79. doi: 10.1016/j.micromeso.2006.09.018
20. [20]
  (20) Serna-Guerrero, R.; Belmabkhout, Y.; Sayari, A. Chem. Eng. J.2010, 158, 513. doi: 10.1016/j.cej.2010.01.041(20) Serna-Guerrero, R.; Belmabkhout, Y.; Sayari, A. Chem. Eng. J.2010, 158, 513. doi: 10.1016/j.cej.2010.01.041
21. [21]
  (21) Son,W. J.; Choi, J. S.; Ahn,W. S. Microporous Mesoporous Mat. 2008, 113, 31. doi: 10.1016/j.micromeso.2007.10.049(21) Son,W. J.; Choi, J. S.; Ahn,W. S. Microporous Mesoporous Mat. 2008, 113, 31. doi: 10.1016/j.micromeso.2007.10.049
22. [22]
  (22) Ma, X.;Wang, X.; Song, C. J. Am. Chem. Soc. 2009, 131, 5777.doi: 10.1021/ja8074105(22) Ma, X.;Wang, X.; Song, C. J. Am. Chem. Soc. 2009, 131, 5777.doi: 10.1021/ja8074105
23. [23]
  (23) Qi, G.;Wang, Y.; Estevez, L.; Duan, X.; Anako, N.; Park, A. H.A. Energy Environ. Sci. 2011, 4, 444. doi: 10.1039/c0ee00213e(23) Qi, G.;Wang, Y.; Estevez, L.; Duan, X.; Anako, N.; Park, A. H.A. Energy Environ. Sci. 2011, 4, 444. doi: 10.1039/c0ee00213e
24. [24]
  (24) Zhang, H. D. Mater. Rev. 2009, 23, 93. [张海东. 材料导报,2009, 23, 93.](24) Zhang, H. D. Mater. Rev. 2009, 23, 93. [张海东. 材料导报,2009, 23, 93.]
25. [25]
  (25) Subagyono, D. J. N.; Liang, Z.; Knowles, G. P.; Chaffee, A. L.Chem. Eng. Res. Des. 2011, 89, 1647. doi: 10.1016/j.cherd.2011.02.019(25) Subagyono, D. J. N.; Liang, Z.; Knowles, G. P.; Chaffee, A. L.Chem. Eng. Res. Des. 2011, 89, 1647. doi: 10.1016/j.cherd.2011.02.019
26. [26]
  (26) Zou, Z. C.;Wei, Q.; Na,W.; Sun, H.; Nei, Z. R. J. Inorg. Mater.2009, 24, 702. [邹泽昌, 韦奇, 纳薇, 孙慧, 聂祚仁. 无机材料学报, 2009, 24, 702.] doi: 10.3724/SP.J.1077.2009.00702(26) Zou, Z. C.;Wei, Q.; Na,W.; Sun, H.; Nei, Z. R. J. Inorg. Mater.2009, 24, 702. [邹泽昌, 韦奇, 纳薇, 孙慧, 聂祚仁. 无机材料学报, 2009, 24, 702.] doi: 10.3724/SP.J.1077.2009.00702
27. [27]
  (27) Yan, X.; Zhang, L.; Zhang, Y.; Qiao, K.; Yan, Z.; Komarneni, S.Chem. Eng. J. 2011, 168, 918. doi: 10.1016/j.cej.2011.01.066(27) Yan, X.; Zhang, L.; Zhang, Y.; Qiao, K.; Yan, Z.; Komarneni, S.Chem. Eng. J. 2011, 168, 918. doi: 10.1016/j.cej.2011.01.066
28. [28]
  (28) Qi, G.; Fu, L.; Choi, B. H.; Giannelis, E. P. Energy Environ. Sci.2012, 5, 7368. doi: 10.1039/c2ee21394j(28) Qi, G.; Fu, L.; Choi, B. H.; Giannelis, E. P. Energy Environ. Sci.2012, 5, 7368. doi: 10.1039/c2ee21394j
29. [29]
  (29) Zhao, J.; Simeon, F.;Wang, Y.; Luo, G.; Hatton, T. A. RSC Adv.2012, 2, 6509. doi: 10.1039/c2ra20149f(29) Zhao, J.; Simeon, F.;Wang, Y.; Luo, G.; Hatton, T. A. RSC Adv.2012, 2, 6509. doi: 10.1039/c2ra20149f
30. [30]
  (30) Feng, X. X.; Hu, G. S.; Hu, X.; Xie, G. Q.; Xie, Y. L.; Lu, J. Q.;Luo, M. F. Ind. Eng. Chem. Res. 2013, 52, 4221. doi: 10.1021/ie301946p(30) Feng, X. X.; Hu, G. S.; Hu, X.; Xie, G. Q.; Xie, Y. L.; Lu, J. Q.;Luo, M. F. Ind. Eng. Chem. Res. 2013, 52, 4221. doi: 10.1021/ie301946p
31. [31]
  (31) Schmidt-Winkel, P.; Lukens,W.W.; Yang, P.; Mar lese, D. I.;Lettow, J. S.; Ying, J. Y.; Stucky, G. D. Chem. Mater. 2000, 12,686. doi: 10.1021/cm991097v(31) Schmidt-Winkel, P.; Lukens,W.W.; Yang, P.; Mar lese, D. I.;Lettow, J. S.; Ying, J. Y.; Stucky, G. D. Chem. Mater. 2000, 12,686. doi: 10.1021/cm991097v
32. [32]
  (32) Harlick, P. J. E.; Sayari, A. Ind. Eng. Chem. Res. 2006, 45,3248. doi: 10.1021/ie051286p(32) Harlick, P. J. E.; Sayari, A. Ind. Eng. Chem. Res. 2006, 45,3248. doi: 10.1021/ie051286p
33. [33]
  (33) Franchi, R. S.; Harlick, P. J. E.; Sayari, A. Ind. Eng. Chem. Res.2005, 44, 8007. doi: 10.1021/ie0504194
  (33) Franchi, R. S.; Harlick, P. J. E.; Sayari, A. Ind. Eng. Chem. Res.2005, 44, 8007. doi: 10.1021/ie0504194

扫一扫看文章

计量

PDF下载量: 703
文章访问数: 1588
HTML全文浏览量: 46

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

五乙烯六胺修饰的MCF基吸附剂的制备及其CO₂吸附性能研究

English

Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO₂ Adsorption

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

五乙烯六胺修饰的MCF基吸附剂的制备及其CO2吸附性能研究

English

Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO2 Adsorption

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

五乙烯六胺修饰的MCF基吸附剂的制备及其CO₂吸附性能研究

Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO₂ Adsorption

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs