还原剂对多孔阳极氧化铝纳米孔道结构的影响

引用本文: 朱绪飞, 韩华, 马宏图, 路超, 戚卫星, 徐晨. 还原剂对多孔阳极氧化铝纳米孔道结构的影响[J]. 物理化学学报, doi: 10.3866/PKU.WHXB201208151 shu

Citation: ZHU Xu-Fei, HAN Hua, MA Hong-Tu, LU Chao, QI Wei-Xing, XU Chen. Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina[J]. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB201208151 shu

还原剂对多孔阳极氧化铝纳米孔道结构的影响

朱绪飞 ^1, ,
韩华 ^2, ,
马宏图 ^2, ,
路超 ^1, ,
戚卫星 ^1, ,
徐晨 ^1,

基金项目:
国家自然科学基金(61171043, 51077072) (61171043, 51077072)

国家科技重大专项资金(2009ZX01021-002)资助项目 (2009ZX01021-002)

摘要:

多孔阳极氧化铝(PAA)和多孔阳极氧化钛纳米管(PATNT)的结构调控近年来倍受关注. 在形成机理尚不清楚的情况下, 对PAA和PATNT的结构调控很难避免盲目性. 为验证“氧气气泡模具”可以形成纳米孔道这个新观点, 本文采用化学方法对PAA的结构进行调控, 成功地引入了一种还原剂来吸收纳米孔道中的氧气气泡. 在添加还原剂的草酸溶液中得到了一种特殊的阳极氧化铝膜. 研究了还原剂的含量对磷酸溶液中形成PAA孔道结构的影响, 结果表明随着还原剂含量的增加, PAA的孔道直径逐渐减小, 有序性降低. 对比了添加还原剂前后阳极氧化过程的电压-时间曲线的差异, 结果表明, 在含有还原剂溶液中制备的阳极氧化铝膜的导电性明显提高. 在密封的条件下, 还原剂能吸收掉孔道中的氧气, 使气泡模具效应消失, 得到完全的致密型氧化膜. 这些实验事实充分证明PAA中有序孔道的形成是氧气气泡模具效应的结果.

关键词:

English

Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina

1.
1 Key Laboratory of Soft Chemistry and Functional Materials of Education Ministry, Nanjing University of Science & Technology, Nanjing 210094, P. R. China;
2 The National Engineering and Technology Research Center for ASIC Design, Institute of Automation, Chinese Academy of Sciences, Beijing 100190, P. R. China
Received Date: 28 May 2012
Available Online: 17 October 2012
Fund Project:
国家自然科学基金(61171043, 51077072)

国家科技重大专项资金(2009ZX01021-002)资助项目

Abstract:

In recent years, attention has been focused on adjustment and control of the nanostructures of porous anodic alumina (PAA) and porous anodic TiO₂ nanotubes (PATNT). Because the formation mechanism of PAA and PATNT is still unclear, it is difficult to adjust the nanostructures of PAA and PATNT. To validate the novel viewpoint of the nanopore resulting from an oxygen bubble mold, an innovative chemical approach was used to adjust the PAA nanostructures. One successful approach is to use a reducer to absorb the oxygen bubbles in the nanopores. A novel anodic alumina film was obtained in a mixed solution of the reducer and oxalic acid. The influence of the reducer on the PAA nanostructures which formed in H₃PO₄ solution was investigated in detail. The experimental results showed that the regularity and the diameters of the nanopores in the PAA decreased as the reducer content increased. The differences in the voltage-time curves between electrolytes with and without the reducer were analyzed quantitatively. The results showed that the conductivity of the anodic oxide film that formed in the electrolyte with the reducer was better than that in the electrolyte without the reducer. When aluminum anodizes in a sealed case, oxygen bubbles are easily absorbed by the reducer, the oxygen bubble mold effect disappears, and a compact alumina film is obtained. Overall, these results clearly demonstrate that nanopores result from the oxygen bubble mold effect.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

还原剂对多孔阳极氧化铝纳米孔道结构的影响

English

Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina

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CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

还原剂对多孔阳极氧化铝纳米孔道结构的影响

English

Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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